Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)

The title compound, [Mn(C(11)H(11)N(2)O(3))(2)(H(2)O)(2)], consists of discrete mononuclear complex mol­ecules. The Mn(II) atom is located on an inversion center and coordinated by two N atoms and two O atoms, each pair in a trans mode, from two 3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimid...

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Detalles Bibliográficos
Autores principales: Sun, Yu, Jiang, Xin-Dong, Li, Xiu-Bing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961442/
https://www.ncbi.nlm.nih.gov/pubmed/21202488
http://dx.doi.org/10.1107/S160053680801369X
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author Sun, Yu
Jiang, Xin-Dong
Li, Xiu-Bing
author_facet Sun, Yu
Jiang, Xin-Dong
Li, Xiu-Bing
author_sort Sun, Yu
collection PubMed
description The title compound, [Mn(C(11)H(11)N(2)O(3))(2)(H(2)O)(2)], consists of discrete mononuclear complex mol­ecules. The Mn(II) atom is located on an inversion center and coordinated by two N atoms and two O atoms, each pair in a trans mode, from two 3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and by two water mol­ecules. The coordination geometry around the Mn(II) atom is slightly distorted octa­hedral. Mol­ecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-29614422010-12-30 Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II) Sun, Yu Jiang, Xin-Dong Li, Xiu-Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(11)H(11)N(2)O(3))(2)(H(2)O)(2)], consists of discrete mononuclear complex mol­ecules. The Mn(II) atom is located on an inversion center and coordinated by two N atoms and two O atoms, each pair in a trans mode, from two 3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olate ligands and by two water mol­ecules. The coordination geometry around the Mn(II) atom is slightly distorted octa­hedral. Mol­ecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961442/ /pubmed/21202488 http://dx.doi.org/10.1107/S160053680801369X Text en © Sun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sun, Yu
Jiang, Xin-Dong
Li, Xiu-Bing
Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)
title Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)
title_full Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)
title_fullStr Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)
title_full_unstemmed Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)
title_short Diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) N (1),O (9)]manganese(II)
title_sort diaqua­bis[3-(2-hydroxy­ethyl)-2-methyl-4-oxopyrido[1,2-a]pyrimidin-9-olato-κ(2) n (1),o (9)]manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961442/
https://www.ncbi.nlm.nih.gov/pubmed/21202488
http://dx.doi.org/10.1107/S160053680801369X
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AT lixiubing diaquabis32hydroxyethyl2methyl4oxopyrido12apyrimidin9olatok2n1o9manganeseii

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