Cargando…

(1R,4′S)-4-(tert-Butyldimethylsilanoxy)-1-[2,2-dimethyl-3-(p-tolylsulfonyl)-1,3-oxazolidin-4-yl]but-2-yn-1-ol

The chiral title compound, C(22)H(35)NO(5)SSi, is a precursor of novel furanomycin derivatives. It crystallizes with two molecules in the asymmetric unit; these show different conformations of the silyl substitutent, as indicated by the Si—O—C—C torsion angles of 41.4 (7) and −84.5 (5)° in the two...

Descripción completa

Detalles Bibliográficos
Autores principales:	Erdsack, Jörg, Schürmann, Markus, Preut, Hans, Krause, Norbert
Formato:	Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2008
Materias:	Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961448/ https://www.ncbi.nlm.nih.gov/pubmed/21202678 http://dx.doi.org/10.1107/S1600536808014906

Ejemplares similares

Triphenyl(prop-2-yn-1-yl)silane
por: Nelson, Björn, et al.
Publicado: (2012)

(4R)-4-Benzyl-3-{(4S)-4-chloro-4-[(S)-2,2-dimethyl-1,3-dioxolan-4-yl]butanoyl}-1,3-oxazolidin-2-one
por: Börding, Sandra, et al.
Publicado: (2011)

1,2-Bis(p-tolylsulfonyl)hydrazine
por: Zhang, Wei-Fen, et al.
Publicado: (2008)

4-(3,4-Dimethyl-5-phenyl-1,3-oxazolidin-2-yl)-2-methoxyphenol
por: Asaruddin, Mohd Razip, et al.
Publicado: (2010)

4,5-Dimethyl-2-phenyl-1-(p-tolyl)-1H-imidazole
por: Gayathri, P., et al.
Publicado: (2010)

4-Phenylsulfonyl-2-(p-tolylsulfonyl)-1H,8H-pyrrolo[2,3-b]indole
por: Badenock, Jeanese C., et al.
Publicado: (2010)

2,2,4-Trimethyl-5-(4-tolylsulfonyl)-2,3,4,5-tetrahydro-1H-1,5-benzodiazepine
por: Ravichandran, K., et al.
Publicado: (2009)

3-(4,6-Dichloro-1,3,5-triazin-2-yl)-2,2-dimethyl-1,3-oxazolidine
por: Zou, Ye-cheng, et al.
Publicado: (2012)

N-(p-Tolylsulfonyl)-l-asparagine
por: Arshad, Muhammad Nadeem, et al.
Publicado: (2010)

(2SR,3SR)-Isopropyl 3-{[dimethyl(phenyl)silyl]methyl}-2-hydroxy-2-vinylpent-4-enoate
por: Nelson, Bjoern, et al.
Publicado: (2010)

2-Bromo-4-(3,4-dimethyl-5-phenyl-1,3-oxazolidin-2-yl)-6-methoxyphenol
por: Hariono, Maywan, et al.
Publicado: (2011)

(±)-syn-Isopropyl 4-(1,1,1,3,3,3-hexafluoropropan-2-yloxy)-1-hydroxy-3-methyl-2-(prop-1-ynyl)cyclopent-2-enecarboxylate
por: Gille, Annika, et al.
Publicado: (2009)

(E)-3,5-Dimethyl-1-p-tolyl-4-(p-tolyldiazenyl)-1H-pyrazole
por: Bustos, Carlos, et al.
Publicado: (2012)

7,7-Dimethyl-4a-(3-methyl-2-butenyl)-2-oxo-4a,5,6,7-tetrahydro-2H-chromen-4-yl benzoate
por: Möws, Katrin, et al.
Publicado: (2009)

(4S)-(−)-4-Benzyl-2,2-dimethyl-3-o-toluoyl-1,3-oxazolidine
por: Gzella, Andrzej K., et al.
Publicado: (2010)

(1E)-6-Methoxy-3,4-dihydronaphthalen-1(2H)-one O-(p-tolylsulfonyl)oxime
por: Han, Rong-Bi, et al.
Publicado: (2010)

(3aR*,7aS*)-1-(p-Tolylsulfonyl)perhydroindol-2-one
por: Fang, Lei, et al.
Publicado: (2010)

3-{2-[(3-{(E)-2-[4-(Dimethylamino)phenyl]ethenyl}quinoxalin-2-yl)oxy]ethyl}-1,3-oxazolidin-2-one monohydrate
por: Ramli, Youssef, et al.
Publicado: (2011)

Bis[4-(2-isopropyl-2H-tetrazol-5-yl)phenyl]dimethylsilane
por: Wang, Peng, et al.
Publicado: (2011)

(4S)-4-Benzyl-N-{[(4S)-4-benzyl-2-oxo-1,3-oxazolidin-3-yl]sulfonyl}-2-oxo-1,3-oxazolidine-3-carboxamide
por: Berredjem, Malika, et al.
Publicado: (2010)

Crystal structure of (E)-1-(2,4-dinitrophenyl)-2-[(E)-5-phenyl-1-(p-tolyl)pent-2-en-4-yn-1-ylidene]hydrazine
por: Golovanov, Alexander A., et al.
Publicado: (2015)

4-(4-Ethoxybenzyl)-1,3-oxazolidin-2-one
por: Wang, Hong-Yong, et al.
Publicado: (2009)

3-[Bis(p-tolylsulfonyl)amino]-N-(4-chlorobenzyl)-6-(3,4-dichlorophenyl)thieno[2,3-b]pyridine-2-carboxamide
por: He, Hai-Yun, et al.
Publicado: (2011)

4-(Prop-2-yn-1-yloxy)benzaldehyde
por: Doi, Ikue, et al.
Publicado: (2012)

4,6-Dimethyl-2-(naphthalen-1-yl)pyrimidine
por: Zhang, Xiao-Xue, et al.
Publicado: (2011)

(S)-3-Dimethylamino-2-{(4S,5R)-5-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-1,3-dioxolan-4-yl}-2-hydroxypropanoic acid
por: Jenkinson, Sarah F., et al.
Publicado: (2007)

4-(4-Methylphenyl)-2-(prop-2-yn-1-yl)phthalazin-1(2H)-one
por: Usha, M. K., et al.
Publicado: (2014)

(4S)-4-[(R)-Chloro(4-nitrophenyl)methyl]-1,3-oxazolidin-2-one
por: Gaumet, V., et al.
Publicado: (2013)

7,7-Dimethyl-3,3,4a-tris(3-methylbut-2-enyl)-4a,5,6,7-tetrahydro-2H-chromene-2,4(3H)-dione
por: Möws, Katrin, et al.
Publicado: (2009)

2,6-Dimethyl-4-(1,3,4-oxadiazol-2-yl)quinoline
por: Kashaev, Artyom G., et al.
Publicado: (2010)

2-(2,2-Dimethyl-2,3-dihydro-1-benzofuran-7-yloxy)-N-(o-tolyl)acetamide
por: Li, Wen-Sheng, et al.
Publicado: (2010)

4,6-Dimethyl-2-p-tolylpyrimidine
por: Xu, Chen, et al.
Publicado: (2009)

3-(2-Pyridyl)-5-(4-pyridyl)-4-(p-tolyl)-1H-1,2,4-triazole
por: Yuan, Lu-Tong, et al.
Publicado: (2009)

N-(2,4-Dimethylphenyl)-2,4-dimethylbenzenesulfonamide
por: Nirmala, P. G., et al.
Publicado: (2010)

4-(Prop-2-yn-1-yloxy)benzene-1,2-dicarbonitrile
por: Chin, Yee Jan, et al.
Publicado: (2012)

Comparison of the crystal structures of 4,4′-bis[3-(4-methylpiperidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl and 4,4′-bis[3-(2,2,6,6-tetramethylpiperidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl
por: Wan, Anqi, et al.
Publicado: (2015)

2-(1H-Imidazol-1-yl)-4,6-dimethylpyrimidine
por: Yu, Dao-Hui, et al.
Publicado: (2011)

{1-[(3,5-Dimethyl-4H-1,2,4-triazol-4-yl)imino]ethyl}ferrocene
por: Hao, Xin-Qi, et al.
Publicado: (2008)

2-(4-Fluorophenyl)-4,5-dimethyl-1-(4-methylphenyl)-1H-imidazole
por: Gayathri, P., et al.
Publicado: (2010)

Crystal structure of 1-(2-chloroacetyl)-3,3-dimethyl-2,6-di-p-tolylpiperidin-4-one
por: Jothivel, S., et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_255ld8qjga0im40jrb5ihi095t