Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate

In the title compound, [CuI(C(13)H(12)N(2)S)(2)]·H(2)O, each Cu(I) ion is coordinated by two S atoms [Cu—S 2.2282 (16), 2.2377 (15) Å] from two N,N′-diphenyl­thio­urea ligands and one iodide ion [Cu—I 2.5170 (11) Å] in a trigonal planar geometry. The uncoordinated water mol­ecules are involved in N—...

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Detalles Bibliográficos
Autores principales: Jia, Li, Kong, Lingqian, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961451/
https://www.ncbi.nlm.nih.gov/pubmed/21202456
http://dx.doi.org/10.1107/S1600536808007861
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author Jia, Li
Kong, Lingqian
Li, Dacheng
author_facet Jia, Li
Kong, Lingqian
Li, Dacheng
author_sort Jia, Li
collection PubMed
description In the title compound, [CuI(C(13)H(12)N(2)S)(2)]·H(2)O, each Cu(I) ion is coordinated by two S atoms [Cu—S 2.2282 (16), 2.2377 (15) Å] from two N,N′-diphenyl­thio­urea ligands and one iodide ion [Cu—I 2.5170 (11) Å] in a trigonal planar geometry. The uncoordinated water mol­ecules are involved in N—H⋯O hydrogen-bonding [N⋯O 2.947 (5), 3.055 (5) Å], which link the mol­ecules into chains extended in the [101] direction. These chains are further paired by weak inter­molecular O—H⋯S hydrogen bonds [O⋯S 3.490 (4) Å].
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spelling pubmed-29614512010-12-30 Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate Jia, Li Kong, Lingqian Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuI(C(13)H(12)N(2)S)(2)]·H(2)O, each Cu(I) ion is coordinated by two S atoms [Cu—S 2.2282 (16), 2.2377 (15) Å] from two N,N′-diphenyl­thio­urea ligands and one iodide ion [Cu—I 2.5170 (11) Å] in a trigonal planar geometry. The uncoordinated water mol­ecules are involved in N—H⋯O hydrogen-bonding [N⋯O 2.947 (5), 3.055 (5) Å], which link the mol­ecules into chains extended in the [101] direction. These chains are further paired by weak inter­molecular O—H⋯S hydrogen bonds [O⋯S 3.490 (4) Å]. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961451/ /pubmed/21202456 http://dx.doi.org/10.1107/S1600536808007861 Text en © Jia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, Li
Kong, Lingqian
Li, Dacheng
Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate
title Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate
title_full Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate
title_fullStr Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate
title_full_unstemmed Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate
title_short Bis­(N,N′-diphenyl­thio­urea)iodido­copper(I) monohydrate
title_sort bis­(n,n′-diphenyl­thio­urea)iodido­copper(i) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961451/
https://www.ncbi.nlm.nih.gov/pubmed/21202456
http://dx.doi.org/10.1107/S1600536808007861
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AT konglingqian bisnndiphenylthioureaiodidocopperimonohydrate
AT lidacheng bisnndiphenylthioureaiodidocopperimonohydrate

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