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2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide
In the molecule of the title compound, C(16)H(18)N(4)O(4), the dihedral angle between the mean planes of the two benzene rings is 56.76 (5)°. The crystal structure reveals extensive intermolecular hydrogen bonds between carbonyl O atoms and primary amines, as well as between primary and secondary...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961455/ https://www.ncbi.nlm.nih.gov/pubmed/21202641 http://dx.doi.org/10.1107/S1600536808014864 |
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author | Ibad, Farooq Mustafa, Asra Shah, Muhammad Raza VanDerveer, Donald |
author_facet | Ibad, Farooq Mustafa, Asra Shah, Muhammad Raza VanDerveer, Donald |
author_sort | Ibad, Farooq |
collection | PubMed |
description | In the molecule of the title compound, C(16)H(18)N(4)O(4), the dihedral angle between the mean planes of the two benzene rings is 56.76 (5)°. The crystal structure reveals extensive intermolecular hydrogen bonds between carbonyl O atoms and primary amines, as well as between primary and secondary amines of hydrazide, forming rings of R (2) (2)(10) and R (2) (2)(6) motifs, respectively. The structure is further stabilized by intramolecular and non-classical hydrogen bonds of the types N—H⋯O and C—H⋯O, respectively. The structure does not show any π–π interactions. |
format | Text |
id | pubmed-2961455 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29614552010-12-30 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide Ibad, Farooq Mustafa, Asra Shah, Muhammad Raza VanDerveer, Donald Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(16)H(18)N(4)O(4), the dihedral angle between the mean planes of the two benzene rings is 56.76 (5)°. The crystal structure reveals extensive intermolecular hydrogen bonds between carbonyl O atoms and primary amines, as well as between primary and secondary amines of hydrazide, forming rings of R (2) (2)(10) and R (2) (2)(6) motifs, respectively. The structure is further stabilized by intramolecular and non-classical hydrogen bonds of the types N—H⋯O and C—H⋯O, respectively. The structure does not show any π–π interactions. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961455/ /pubmed/21202641 http://dx.doi.org/10.1107/S1600536808014864 Text en © Ibad et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ibad, Farooq Mustafa, Asra Shah, Muhammad Raza VanDerveer, Donald 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide |
title | 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide |
title_full | 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide |
title_fullStr | 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide |
title_full_unstemmed | 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide |
title_short | 2,2′-(Biphenyl-2,2′-diyldioxy)diacetohydrazide |
title_sort | 2,2′-(biphenyl-2,2′-diyldioxy)diacetohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961455/ https://www.ncbi.nlm.nih.gov/pubmed/21202641 http://dx.doi.org/10.1107/S1600536808014864 |
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