Cargando…

2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide

In the mol­ecule of the title compound, C(16)H(18)N(4)O(4), the dihedral angle between the mean planes of the two benzene rings is 56.76 (5)°. The crystal structure reveals extensive inter­molecular hydrogen bonds between carbonyl O atoms and primary amines, as well as between primary and secondary...

Descripción completa

Detalles Bibliográficos
Autores principales: Ibad, Farooq, Mustafa, Asra, Shah, Muhammad Raza, VanDerveer, Donald
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961455/
https://www.ncbi.nlm.nih.gov/pubmed/21202641
http://dx.doi.org/10.1107/S1600536808014864
_version_ 1782188986877345792
author Ibad, Farooq
Mustafa, Asra
Shah, Muhammad Raza
VanDerveer, Donald
author_facet Ibad, Farooq
Mustafa, Asra
Shah, Muhammad Raza
VanDerveer, Donald
author_sort Ibad, Farooq
collection PubMed
description In the mol­ecule of the title compound, C(16)H(18)N(4)O(4), the dihedral angle between the mean planes of the two benzene rings is 56.76 (5)°. The crystal structure reveals extensive inter­molecular hydrogen bonds between carbonyl O atoms and primary amines, as well as between primary and secondary amines of hydrazide, forming rings of R (2) (2)(10) and R (2) (2)(6) motifs, respectively. The structure is further stabilized by intra­molecular and non-classical hydrogen bonds of the types N—H⋯O and C—H⋯O, respectively. The structure does not show any π–π inter­actions.
format Text
id pubmed-2961455
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29614552010-12-30 2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide Ibad, Farooq Mustafa, Asra Shah, Muhammad Raza VanDerveer, Donald Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(16)H(18)N(4)O(4), the dihedral angle between the mean planes of the two benzene rings is 56.76 (5)°. The crystal structure reveals extensive inter­molecular hydrogen bonds between carbonyl O atoms and primary amines, as well as between primary and secondary amines of hydrazide, forming rings of R (2) (2)(10) and R (2) (2)(6) motifs, respectively. The structure is further stabilized by intra­molecular and non-classical hydrogen bonds of the types N—H⋯O and C—H⋯O, respectively. The structure does not show any π–π inter­actions. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961455/ /pubmed/21202641 http://dx.doi.org/10.1107/S1600536808014864 Text en © Ibad et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ibad, Farooq
Mustafa, Asra
Shah, Muhammad Raza
VanDerveer, Donald
2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
title 2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
title_full 2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
title_fullStr 2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
title_full_unstemmed 2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
title_short 2,2′-(Biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
title_sort 2,2′-(biphenyl-2,2′-diyldi­oxy)diaceto­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961455/
https://www.ncbi.nlm.nih.gov/pubmed/21202641
http://dx.doi.org/10.1107/S1600536808014864
work_keys_str_mv AT ibadfarooq 22biphenyl22diyldioxydiacetohydrazide
AT mustafaasra 22biphenyl22diyldioxydiacetohydrazide
AT shahmuhammadraza 22biphenyl22diyldioxydiacetohydrazide
AT vanderveerdonald 22biphenyl22diyldioxydiacetohydrazide