Bromido-1κBr-tricarbonyl-2κ(3) C-(2η(5)-cyclo­penta­dien­yl)molybdenum(I)tungsten(I)(W—Mo)

The title compound, [WMoBr(C(5)H(5))(CO)(3)], is built up from a pseudo-square-pyramidal piano-stool coordination around the Mo atom, the important geometry being Mo—W = 2.6872 (7) Å, W—Br = 2.5591 (9) Å and Mo—W—Br = 158.35 (3)°.

Detalles Bibliográficos
Autores principales: Onani, Martin O., Gertenbach, Jan-André, Bala, Muhammad D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961464/
https://www.ncbi.nlm.nih.gov/pubmed/21202470
http://dx.doi.org/10.1107/S1600536808012828
Descripción
Sumario:The title compound, [WMoBr(C(5)H(5))(CO)(3)], is built up from a pseudo-square-pyramidal piano-stool coordination around the Mo atom, the important geometry being Mo—W = 2.6872 (7) Å, W—Br = 2.5591 (9) Å and Mo—W—Br = 158.35 (3)°.

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