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Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate

The title compound, C(17)H(16)N(2)S(2), a dithio­carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl­idine group. The 3-phenyl­prop-2-enyl­idene and dithio­carbazate fragments lie essentially in the same plane, with a maximum deviation from t...

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Detalles Bibliográficos
Autores principales: Tarafder, M. T. H., Crouse, K. A., Islam, M. Toihidul, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961473/
https://www.ncbi.nlm.nih.gov/pubmed/21202563
http://dx.doi.org/10.1107/S1600536808013354
Descripción
Sumario:The title compound, C(17)H(16)N(2)S(2), a dithio­carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl­idine group. The 3-phenyl­prop-2-enyl­idene and dithio­carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenyl­prop-2-enyl­idene and the benzyl group is 77.78 (7)°. In the crystal structure, mol­ecules are linked by an N—H⋯S hydrogen bond and a weak C—H⋯S inter­action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C—H⋯π inter­actions.