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Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate
The title compound, C(17)H(16)N(2)S(2), a dithiocarbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenylidine group. The 3-phenylprop-2-enylidene and dithiocarbazate fragments lie essentially in the same plane, with a maximum deviation from t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961473/ https://www.ncbi.nlm.nih.gov/pubmed/21202563 http://dx.doi.org/10.1107/S1600536808013354 |
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author | Tarafder, M. T. H. Crouse, K. A. Islam, M. Toihidul Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Tarafder, M. T. H. Crouse, K. A. Islam, M. Toihidul Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Tarafder, M. T. H. |
collection | PubMed |
description | The title compound, C(17)H(16)N(2)S(2), a dithiocarbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenylidine group. The 3-phenylprop-2-enylidene and dithiocarbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenylprop-2-enylidene and the benzyl group is 77.78 (7)°. In the crystal structure, molecules are linked by an N—H⋯S hydrogen bond and a weak C—H⋯S interaction involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C—H⋯π interactions. |
format | Text |
id | pubmed-2961473 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29614732010-12-30 Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate Tarafder, M. T. H. Crouse, K. A. Islam, M. Toihidul Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)N(2)S(2), a dithiocarbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenylidine group. The 3-phenylprop-2-enylidene and dithiocarbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenylprop-2-enylidene and the benzyl group is 77.78 (7)°. In the crystal structure, molecules are linked by an N—H⋯S hydrogen bond and a weak C—H⋯S interaction involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C—H⋯π interactions. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961473/ /pubmed/21202563 http://dx.doi.org/10.1107/S1600536808013354 Text en © Tarafder et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tarafder, M. T. H. Crouse, K. A. Islam, M. Toihidul Chantrapromma, Suchada Fun, Hoong-Kun Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate |
title | Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate |
title_full | Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate |
title_fullStr | Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate |
title_full_unstemmed | Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate |
title_short | Benzyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate |
title_sort | benzyl 3-[(e,e)-3-phenylprop-2-enylidene]dithiocarbazate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961473/ https://www.ncbi.nlm.nih.gov/pubmed/21202563 http://dx.doi.org/10.1107/S1600536808013354 |
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