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Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate

The title compound, C(17)H(16)N(2)S(2), a dithio­carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl­idine group. The 3-phenyl­prop-2-enyl­idene and dithio­carbazate fragments lie essentially in the same plane, with a maximum deviation from t...

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Autores principales: Tarafder, M. T. H., Crouse, K. A., Islam, M. Toihidul, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961473/
https://www.ncbi.nlm.nih.gov/pubmed/21202563
http://dx.doi.org/10.1107/S1600536808013354
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author Tarafder, M. T. H.
Crouse, K. A.
Islam, M. Toihidul
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Tarafder, M. T. H.
Crouse, K. A.
Islam, M. Toihidul
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Tarafder, M. T. H.
collection PubMed
description The title compound, C(17)H(16)N(2)S(2), a dithio­carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl­idine group. The 3-phenyl­prop-2-enyl­idene and dithio­carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenyl­prop-2-enyl­idene and the benzyl group is 77.78 (7)°. In the crystal structure, mol­ecules are linked by an N—H⋯S hydrogen bond and a weak C—H⋯S inter­action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C—H⋯π inter­actions.
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spelling pubmed-29614732010-12-30 Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate Tarafder, M. T. H. Crouse, K. A. Islam, M. Toihidul Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(16)N(2)S(2), a dithio­carbazate derivative, adopts an EE configuration with respect to the C=C and C=N double bonds of the propenyl­idine group. The 3-phenyl­prop-2-enyl­idene and dithio­carbazate fragments lie essentially in the same plane, with a maximum deviation from that plane of 0.074 (2) Å, while the dihedral angle between the 3-phenyl­prop-2-enyl­idene and the benzyl group is 77.78 (7)°. In the crystal structure, mol­ecules are linked by an N—H⋯S hydrogen bond and a weak C—H⋯S inter­action involving the terminal thione S atom, forming dimers that are arranged into sheets parallel to the bc plane. The crystal structure is also stabilized by C—H⋯π inter­actions. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961473/ /pubmed/21202563 http://dx.doi.org/10.1107/S1600536808013354 Text en © Tarafder et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tarafder, M. T. H.
Crouse, K. A.
Islam, M. Toihidul
Chantrapromma, Suchada
Fun, Hoong-Kun
Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_full Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_fullStr Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_full_unstemmed Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_short Benzyl 3-[(E,E)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
title_sort benzyl 3-[(e,e)-3-phenyl­prop-2-enyl­idene]dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961473/
https://www.ncbi.nlm.nih.gov/pubmed/21202563
http://dx.doi.org/10.1107/S1600536808013354
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