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(2-Hydroxy­phenyl­imido-κN)(methano­lato-κO)[2-(2-oxidobenzyl­ideneamino)phenolato-κ(2) O,N,O′](triphenyl­phosphine-κP)rhenium(V)

In the neutral title compound, [Re(C(6)H(5)NO)(C(13)H(9)NO(2))(CH(3)O)(C(18)H(15)P)], an 18-valence-electron complex, the Re(V) ion lies in an octa­hedral coordination geometry with the tridentate dianionic Schiff base 2-(2-oxidobenzyl­idene­amino)phenolate ligand occupying three equatorial coordina...

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Detalles Bibliográficos
Autores principales: Holland, Jason P., Barnard, Peter J., Dilworth, Jonathan R., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961474/
https://www.ncbi.nlm.nih.gov/pubmed/21202465
http://dx.doi.org/10.1107/S1600536808010684
Descripción
Sumario:In the neutral title compound, [Re(C(6)H(5)NO)(C(13)H(9)NO(2))(CH(3)O)(C(18)H(15)P)], an 18-valence-electron complex, the Re(V) ion lies in an octa­hedral coordination geometry with the tridentate dianionic Schiff base 2-(2-oxidobenzyl­idene­amino)phenolate ligand occupying three equatorial coordination sites, and with the triphenyl­phosphine ligand situated trans to the imine N atom. The Re(V) coordination is completed with a methano­late ligand and a 2-hydroxy­phenyl­imido(2-) ligand. There are two molecules in the asymmetric unit. The crystal structure involves O—H⋯O and C—H⋯O hydrogen bonds. One N and one C atom are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.