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(2-Hydroxyphenylimido-κN)(methanolato-κO)[2-(2-oxidobenzylideneamino)phenolato-κ(2) O,N,O′](triphenylphosphine-κP)rhenium(V)
In the neutral title compound, [Re(C(6)H(5)NO)(C(13)H(9)NO(2))(CH(3)O)(C(18)H(15)P)], an 18-valence-electron complex, the Re(V) ion lies in an octahedral coordination geometry with the tridentate dianionic Schiff base 2-(2-oxidobenzylideneamino)phenolate ligand occupying three equatorial coordina...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961474/ https://www.ncbi.nlm.nih.gov/pubmed/21202465 http://dx.doi.org/10.1107/S1600536808010684 |
Sumario: | In the neutral title compound, [Re(C(6)H(5)NO)(C(13)H(9)NO(2))(CH(3)O)(C(18)H(15)P)], an 18-valence-electron complex, the Re(V) ion lies in an octahedral coordination geometry with the tridentate dianionic Schiff base 2-(2-oxidobenzylideneamino)phenolate ligand occupying three equatorial coordination sites, and with the triphenylphosphine ligand situated trans to the imine N atom. The Re(V) coordination is completed with a methanolate ligand and a 2-hydroxyphenylimido(2-) ligand. There are two molecules in the asymmetric unit. The crystal structure involves O—H⋯O and C—H⋯O hydrogen bonds. One N and one C atom are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3. |
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