(11R,11aS)-11-Hydr­oxy-1,5,11,11a-tetra­hydro-1-benzothieno[2,3-f]indolizin-3(2H)-one

The absolute configuration of the title compound, C(14)H(13)NO(2)S, was assigned from the synthesis and confirmed by the structure determination. The central six-membered ring of the indolizine system adopts an envelope conformation, the greatest deviation from the mean plane of the ring being 0.459...

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Detalles Bibliográficos
Autores principales: Švorc, Ľubomír, Vrábel, Viktor, Kožíšek, Jozef, Marchalín, Štefan, Šafář, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961476/
https://www.ncbi.nlm.nih.gov/pubmed/21202672
http://dx.doi.org/10.1107/S1600536808015456
Descripción
Sumario:The absolute configuration of the title compound, C(14)H(13)NO(2)S, was assigned from the synthesis and confirmed by the structure determination. The central six-membered ring of the indolizine system adopts an envelope conformation, the greatest deviation from the mean plane of the ring being 0.459 (2) Å for the N atom. The benzothieno system is planar [mean deviation = 0.009 (2) Å]. In the crystal structure, mol­ecules form chains parallel to the b axis via inter­molecular O—H⋯O hydrogen bonds.

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