Diaqua­[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]manganese(II)

The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydro­thermal reaction of Mn(NO(3))(2) with picolino­nitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octa­hedral Mn environment contains two planar trans-related N,N′-chelating 5-(2-...

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Detalles Bibliográficos
Autor principal: Wen, Xiao-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961478/
https://www.ncbi.nlm.nih.gov/pubmed/21202460
http://dx.doi.org/10.1107/S1600536808010106
Descripción
Sumario:The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydro­thermal reaction of Mn(NO(3))(2) with picolino­nitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octa­hedral Mn environment contains two planar trans-related N,N′-chelating 5-(2-pyrid­yl)­tetra­zolate ligands in the equatorial plane and two axial water mol­ecules. O—H⋯N hydrogen bonds generate an infinite three-dimensional network.

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