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Diaqua[5-(2-pyridyl)tetrazolato-κ(2) N (1),N (5)]manganese(II)
The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydrothermal reaction of Mn(NO(3))(2) with picolinonitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octahedral Mn environment contains two planar trans-related N,N′-chelating 5-(2-...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961478/ https://www.ncbi.nlm.nih.gov/pubmed/21202460 http://dx.doi.org/10.1107/S1600536808010106 |
| _version_ | 1782188992371884032 |
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| author | Wen, Xiao-Chun |
| author_facet | Wen, Xiao-Chun |
| author_sort | Wen, Xiao-Chun |
| collection | PubMed |
| description | The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydrothermal reaction of Mn(NO(3))(2) with picolinonitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octahedral Mn environment contains two planar trans-related N,N′-chelating 5-(2-pyridyl)tetrazolate ligands in the equatorial plane and two axial water molecules. O—H⋯N hydrogen bonds generate an infinite three-dimensional network. |
| format | Text |
| id | pubmed-2961478 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29614782010-12-30 Diaqua[5-(2-pyridyl)tetrazolato-κ(2) N (1),N (5)]manganese(II) Wen, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the hydrothermal reaction of Mn(NO(3))(2) with picolinonitrile in the presence of NaN(3). The Mn atom lies on an inversion centre. The distorted octahedral Mn environment contains two planar trans-related N,N′-chelating 5-(2-pyridyl)tetrazolate ligands in the equatorial plane and two axial water molecules. O—H⋯N hydrogen bonds generate an infinite three-dimensional network. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961478/ /pubmed/21202460 http://dx.doi.org/10.1107/S1600536808010106 Text en © Xiao-Chun Wen 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wen, Xiao-Chun Diaqua[5-(2-pyridyl)tetrazolato-κ(2) N (1),N (5)]manganese(II) |
| title | Diaqua[5-(2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]manganese(II) |
| title_full | Diaqua[5-(2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]manganese(II) |
| title_fullStr | Diaqua[5-(2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]manganese(II) |
| title_full_unstemmed | Diaqua[5-(2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]manganese(II) |
| title_short | Diaqua[5-(2-pyridyl)tetrazolato-κ(2)
N
(1),N
(5)]manganese(II) |
| title_sort | diaqua[5-(2-pyridyl)tetrazolato-κ(2)
n
(1),n
(5)]manganese(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961478/ https://www.ncbi.nlm.nih.gov/pubmed/21202460 http://dx.doi.org/10.1107/S1600536808010106 |
| work_keys_str_mv | AT wenxiaochun diaqua52pyridyltetrazolatok2n1n5manganeseii |