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(S)-1-(2-Ammonio-3-methylbutyl)-1,2-dihydropyridin-2-iminium dibromide
In the title compound, C(10)H(19)N(3) (2+)·2Br(−), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80 (2)°]. The N atom of the ammonium group is displaced by 1.150 (8) Å from the plane of these three C atoms. The iminium N at...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961482/ https://www.ncbi.nlm.nih.gov/pubmed/21202549 http://dx.doi.org/10.1107/S1600536808012154 |
| Sumario: | In the title compound, C(10)H(19)N(3) (2+)·2Br(−), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80 (2)°]. The N atom of the ammonium group is displaced by 1.150 (8) Å from the plane of these three C atoms. The iminium N atom lies on the opposite side of this plane. The crystal structure is stabilized by hydrogen bonds between the N and Br atoms, as well as by intermolecular C—H⋯Br interactions. |
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