(S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide

In the title compound, C(10)H(19)N(3) (2+)·2Br(−), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80 (2)°]. The N atom of the ammonium group is displaced by 1.150 (8) Å from the plane of these three C atoms. The iminium N at...

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Detalles Bibliográficos
Autores principales: Wang, Yifeng, Zhang, Jixv, Chen, Hui, Luo, Shuping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961482/
https://www.ncbi.nlm.nih.gov/pubmed/21202549
http://dx.doi.org/10.1107/S1600536808012154
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author Wang, Yifeng
Zhang, Jixv
Chen, Hui
Luo, Shuping
author_facet Wang, Yifeng
Zhang, Jixv
Chen, Hui
Luo, Shuping
author_sort Wang, Yifeng
collection PubMed
description In the title compound, C(10)H(19)N(3) (2+)·2Br(−), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80 (2)°]. The N atom of the ammonium group is displaced by 1.150 (8) Å from the plane of these three C atoms. The iminium N atom lies on the opposite side of this plane. The crystal structure is stabilized by hydrogen bonds between the N and Br atoms, as well as by inter­molecular C—H⋯Br inter­actions.
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spelling pubmed-29614822010-12-30 (S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide Wang, Yifeng Zhang, Jixv Chen, Hui Luo, Shuping Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(19)N(3) (2+)·2Br(−), the plane of the three butyl C atoms nearest to the pyridine ring is almost perpendicular to the ring [dihedral angle = 84.80 (2)°]. The N atom of the ammonium group is displaced by 1.150 (8) Å from the plane of these three C atoms. The iminium N atom lies on the opposite side of this plane. The crystal structure is stabilized by hydrogen bonds between the N and Br atoms, as well as by inter­molecular C—H⋯Br inter­actions. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961482/ /pubmed/21202549 http://dx.doi.org/10.1107/S1600536808012154 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Yifeng
Zhang, Jixv
Chen, Hui
Luo, Shuping
(S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
title (S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
title_full (S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
title_fullStr (S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
title_full_unstemmed (S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
title_short (S)-1-(2-Ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
title_sort (s)-1-(2-ammonio-3-methyl­butyl)-1,2-dihydro­pyridin-2-iminium dibromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961482/
https://www.ncbi.nlm.nih.gov/pubmed/21202549
http://dx.doi.org/10.1107/S1600536808012154
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AT luoshuping s12ammonio3methylbutyl12dihydropyridin2iminiumdibromide

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