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4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1)
The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetracarboxylic acid, where both components are centrosymmetric. The component mol...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961488/ https://www.ncbi.nlm.nih.gov/pubmed/21202711 http://dx.doi.org/10.1107/S1600536808011732 |
Sumario: | The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetracarboxylic acid, where both components are centrosymmetric. The component molecules are linked through strong O⋯H⋯N hydrogen bonds, forming chains extending approximately along [[Image: see text]11]. The chains are interconnected by O⋯H⋯O hydrogen bonds and weak stacking interactions involving the pyridyl rings of the 4,4′-bipyridine molecules [centroid–centroid distance = 3.73 (2) Å and interplanar distance = 3.35 (1) Å]. The H atom of the short O⋯H⋯N hydrogen bond is disordered over two positions with site occupancy factors of ca 0.6 and 0.4. One methylene group is disordered over two positions; the site occupancy factors are ca 0.9 and 0.1. |
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