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4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)

The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetra­carboxylic acid, where both components are centrosymmetric. The component mol...

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Detalles Bibliográficos
Autores principales: Najafpour, M. Mahdi, Hołyńska, Małgorzata, Lis, Tadeusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961488/
https://www.ncbi.nlm.nih.gov/pubmed/21202711
http://dx.doi.org/10.1107/S1600536808011732
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author Najafpour, M. Mahdi
Hołyńska, Małgorzata
Lis, Tadeusz
author_facet Najafpour, M. Mahdi
Hołyńska, Małgorzata
Lis, Tadeusz
author_sort Najafpour, M. Mahdi
collection PubMed
description The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetra­carboxylic acid, where both components are centrosymmetric. The component mol­ecules are linked through strong O⋯H⋯N hydrogen bonds, forming chains extending approximately along [[Image: see text]11]. The chains are inter­connected by O⋯H⋯O hydrogen bonds and weak stacking inter­actions involving the pyridyl rings of the 4,4′-bipyridine mol­ecules [centroid–centroid distance = 3.73 (2) Å and inter­planar distance = 3.35 (1) Å]. The H atom of the short O⋯H⋯N hydrogen bond is disordered over two positions with site occupancy factors of ca 0.6 and 0.4. One methylene group is disordered over two positions; the site occupancy factors are ca 0.9 and 0.1.
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spelling pubmed-29614882010-12-30 4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1) Najafpour, M. Mahdi Hołyńska, Małgorzata Lis, Tadeusz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetra­carboxylic acid, where both components are centrosymmetric. The component mol­ecules are linked through strong O⋯H⋯N hydrogen bonds, forming chains extending approximately along [[Image: see text]11]. The chains are inter­connected by O⋯H⋯O hydrogen bonds and weak stacking inter­actions involving the pyridyl rings of the 4,4′-bipyridine mol­ecules [centroid–centroid distance = 3.73 (2) Å and inter­planar distance = 3.35 (1) Å]. The H atom of the short O⋯H⋯N hydrogen bond is disordered over two positions with site occupancy factors of ca 0.6 and 0.4. One methylene group is disordered over two positions; the site occupancy factors are ca 0.9 and 0.1. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961488/ /pubmed/21202711 http://dx.doi.org/10.1107/S1600536808011732 Text en © Najafpour et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Najafpour, M. Mahdi
Hołyńska, Małgorzata
Lis, Tadeusz
4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
title 4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
title_full 4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
title_fullStr 4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
title_full_unstemmed 4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
title_short 4,4′-Bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
title_sort 4,4′-bipyridine–butane-1,2,3,4-tetra­carboxylic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961488/
https://www.ncbi.nlm.nih.gov/pubmed/21202711
http://dx.doi.org/10.1107/S1600536808011732
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