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4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1)
The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetracarboxylic acid, where both components are centrosymmetric. The component mol...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961488/ https://www.ncbi.nlm.nih.gov/pubmed/21202711 http://dx.doi.org/10.1107/S1600536808011732 |
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author | Najafpour, M. Mahdi Hołyńska, Małgorzata Lis, Tadeusz |
author_facet | Najafpour, M. Mahdi Hołyńska, Małgorzata Lis, Tadeusz |
author_sort | Najafpour, M. Mahdi |
collection | PubMed |
description | The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetracarboxylic acid, where both components are centrosymmetric. The component molecules are linked through strong O⋯H⋯N hydrogen bonds, forming chains extending approximately along [[Image: see text]11]. The chains are interconnected by O⋯H⋯O hydrogen bonds and weak stacking interactions involving the pyridyl rings of the 4,4′-bipyridine molecules [centroid–centroid distance = 3.73 (2) Å and interplanar distance = 3.35 (1) Å]. The H atom of the short O⋯H⋯N hydrogen bond is disordered over two positions with site occupancy factors of ca 0.6 and 0.4. One methylene group is disordered over two positions; the site occupancy factors are ca 0.9 and 0.1. |
format | Text |
id | pubmed-2961488 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29614882010-12-30 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) Najafpour, M. Mahdi Hołyńska, Małgorzata Lis, Tadeusz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(8)N(2)·C(8)H(10)O(8), is an example of a system with a short O⋯H⋯N hydrogen bond [O⋯N = 2.565 (3) Å]. The crystal structure comprises a 1:1 adduct between 4,4′-bipyridine and butane-1,2,3,4-tetracarboxylic acid, where both components are centrosymmetric. The component molecules are linked through strong O⋯H⋯N hydrogen bonds, forming chains extending approximately along [[Image: see text]11]. The chains are interconnected by O⋯H⋯O hydrogen bonds and weak stacking interactions involving the pyridyl rings of the 4,4′-bipyridine molecules [centroid–centroid distance = 3.73 (2) Å and interplanar distance = 3.35 (1) Å]. The H atom of the short O⋯H⋯N hydrogen bond is disordered over two positions with site occupancy factors of ca 0.6 and 0.4. One methylene group is disordered over two positions; the site occupancy factors are ca 0.9 and 0.1. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961488/ /pubmed/21202711 http://dx.doi.org/10.1107/S1600536808011732 Text en © Najafpour et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Najafpour, M. Mahdi Hołyńska, Małgorzata Lis, Tadeusz 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
title | 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
title_full | 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
title_fullStr | 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
title_full_unstemmed | 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
title_short | 4,4′-Bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
title_sort | 4,4′-bipyridine–butane-1,2,3,4-tetracarboxylic acid (1/1) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961488/ https://www.ncbi.nlm.nih.gov/pubmed/21202711 http://dx.doi.org/10.1107/S1600536808011732 |
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