(E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone

Crystals of the title compound, C(12)H(10)N(4)O(5), were obtained from a condensation reaction of 2,4-dinitro­phenyl­hydrazine and 2-furyl methyl ketone. The mol­ecule displays a nearly planar structure, and the furan ring is slightly twisted by a dihedral angle of 12.62 (6)° with respect to the phe...

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Detalles Bibliográficos
Autores principales: Shan, Shang, Tian, Yu-Liang, Wang, Shan-Heng, Wang, Wen-Long, Xu, Ying-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961490/
https://www.ncbi.nlm.nih.gov/pubmed/21202661
http://dx.doi.org/10.1107/S1600536808015122
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author Shan, Shang
Tian, Yu-Liang
Wang, Shan-Heng
Wang, Wen-Long
Xu, Ying-Li
author_facet Shan, Shang
Tian, Yu-Liang
Wang, Shan-Heng
Wang, Wen-Long
Xu, Ying-Li
author_sort Shan, Shang
collection PubMed
description Crystals of the title compound, C(12)H(10)N(4)O(5), were obtained from a condensation reaction of 2,4-dinitro­phenyl­hydrazine and 2-furyl methyl ketone. The mol­ecule displays a nearly planar structure, and the furan ring is slightly twisted by a dihedral angle of 12.62 (6)° with respect to the phenyl­hydrazone plane. The face-to-face separation of 3.287 (7) Å between parallel benzene rings of adjacent mol­ecules indicates the existence of π–π stacking between dinitro­phenyl rings in the crystal structure.
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spelling pubmed-29614902010-12-30 (E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone Shan, Shang Tian, Yu-Liang Wang, Shan-Heng Wang, Wen-Long Xu, Ying-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(12)H(10)N(4)O(5), were obtained from a condensation reaction of 2,4-dinitro­phenyl­hydrazine and 2-furyl methyl ketone. The mol­ecule displays a nearly planar structure, and the furan ring is slightly twisted by a dihedral angle of 12.62 (6)° with respect to the phenyl­hydrazone plane. The face-to-face separation of 3.287 (7) Å between parallel benzene rings of adjacent mol­ecules indicates the existence of π–π stacking between dinitro­phenyl rings in the crystal structure. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961490/ /pubmed/21202661 http://dx.doi.org/10.1107/S1600536808015122 Text en © Shan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shan, Shang
Tian, Yu-Liang
Wang, Shan-Heng
Wang, Wen-Long
Xu, Ying-Li
(E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
title (E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
title_full (E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
title_fullStr (E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
title_full_unstemmed (E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
title_short (E)-2-Furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
title_sort (e)-2-furyl methyl ketone 2,4-dinitro­phenyl­hydrazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961490/
https://www.ncbi.nlm.nih.gov/pubmed/21202661
http://dx.doi.org/10.1107/S1600536808015122
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AT wangwenlong e2furylmethylketone24dinitrophenylhydrazone
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