Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride

The title compound, K(4)Sb(2)SnF(14), is built from anionic layers, with an overall composition of [Sb(2)SnF(14)](4−) extending parallel to the ac plane, and K(+) cations. The layers are made up from vertex-sharing centrosymmetric SnF(6) octa­hedra and Sb(2)F(12) dimers. The Sn—F distances are in th...

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Autores principales: Gerasimenko, A. V., Merkulov, E. B., Usol’tseva, T. I.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961491/
https://www.ncbi.nlm.nih.gov/pubmed/21202434
http://dx.doi.org/10.1107/S1600536808012865
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author Gerasimenko, A. V.
Merkulov, E. B.
Usol’tseva, T. I.
author_facet Gerasimenko, A. V.
Merkulov, E. B.
Usol’tseva, T. I.
author_sort Gerasimenko, A. V.
collection PubMed
description The title compound, K(4)Sb(2)SnF(14), is built from anionic layers, with an overall composition of [Sb(2)SnF(14)](4−) extending parallel to the ac plane, and K(+) cations. The layers are made up from vertex-sharing centrosymmetric SnF(6) octa­hedra and Sb(2)F(12) dimers. The Sn—F distances are in the range 1.9581 (14)–1.9611 (17) Å. The Sb polyhedra contain three short terminal Sb—F bonds [1.9380 (14)–2.0696 (15) Å], one short bridging bond [2.0609 (17) Å], one bridging bond of medium length [2.7516 (15) Å], and two longer bridging bonds [3.0471 (18) and 3.117 (2) Å]. The K(+) ions are coordinated by F atoms with coordination numbers 10 and 8, and K—F bond lengths are in the range 2.6235 (16)–3.122 (2) Å.
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spelling pubmed-29614912010-12-30 Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride Gerasimenko, A. V. Merkulov, E. B. Usol’tseva, T. I. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, K(4)Sb(2)SnF(14), is built from anionic layers, with an overall composition of [Sb(2)SnF(14)](4−) extending parallel to the ac plane, and K(+) cations. The layers are made up from vertex-sharing centrosymmetric SnF(6) octa­hedra and Sb(2)F(12) dimers. The Sn—F distances are in the range 1.9581 (14)–1.9611 (17) Å. The Sb polyhedra contain three short terminal Sb—F bonds [1.9380 (14)–2.0696 (15) Å], one short bridging bond [2.0609 (17) Å], one bridging bond of medium length [2.7516 (15) Å], and two longer bridging bonds [3.0471 (18) and 3.117 (2) Å]. The K(+) ions are coordinated by F atoms with coordination numbers 10 and 8, and K—F bond lengths are in the range 2.6235 (16)–3.122 (2) Å. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961491/ /pubmed/21202434 http://dx.doi.org/10.1107/S1600536808012865 Text en © Gerasimenko et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Gerasimenko, A. V.
Merkulov, E. B.
Usol’tseva, T. I.
Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride
title Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride
title_full Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride
title_fullStr Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride
title_full_unstemmed Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride
title_short Tetra­potassium dianti­mony(III) tin(IV) tetra­deca­fluoride
title_sort tetra­potassium dianti­mony(iii) tin(iv) tetra­deca­fluoride
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961491/
https://www.ncbi.nlm.nih.gov/pubmed/21202434
http://dx.doi.org/10.1107/S1600536808012865
work_keys_str_mv AT gerasimenkoav tetrapotassiumdiantimonyiiitinivtetradecafluoride
AT merkuloveb tetrapotassiumdiantimonyiiitinivtetradecafluoride
AT usoltsevati tetrapotassiumdiantimonyiiitinivtetradecafluoride

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