[η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)

The structure of the title compound, [Dy(C(8)H(22)B(4)Si(2))Cl(C(6)H(16)N(2))], reveals that a center of symmetry exists within the dimeric half-sandwich units. Within each half-sandwich, the Dy(III) ion is coordinated by the five-membered ring of the carborane, tetramethylethyl­enediamine and the c...

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Detalles Bibliográficos
Autores principales: Zheng, Chong, Canseco-Melchor, Graciela, Maguire, John A., Hosmane, Narayan S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961499/
https://www.ncbi.nlm.nih.gov/pubmed/21202486
http://dx.doi.org/10.1107/S1600536808013615
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author Zheng, Chong
Canseco-Melchor, Graciela
Maguire, John A.
Hosmane, Narayan S.
author_facet Zheng, Chong
Canseco-Melchor, Graciela
Maguire, John A.
Hosmane, Narayan S.
author_sort Zheng, Chong
collection PubMed
description The structure of the title compound, [Dy(C(8)H(22)B(4)Si(2))Cl(C(6)H(16)N(2))], reveals that a center of symmetry exists within the dimeric half-sandwich units. Within each half-sandwich, the Dy(III) ion is coordinated by the five-membered ring of the carborane, tetramethylethyl­enediamine and the chloride ion.
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spelling pubmed-29614992010-12-30 [η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III) Zheng, Chong Canseco-Melchor, Graciela Maguire, John A. Hosmane, Narayan S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Dy(C(8)H(22)B(4)Si(2))Cl(C(6)H(16)N(2))], reveals that a center of symmetry exists within the dimeric half-sandwich units. Within each half-sandwich, the Dy(III) ion is coordinated by the five-membered ring of the carborane, tetramethylethyl­enediamine and the chloride ion. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961499/ /pubmed/21202486 http://dx.doi.org/10.1107/S1600536808013615 Text en © Zheng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Chong
Canseco-Melchor, Graciela
Maguire, John A.
Hosmane, Narayan S.
[η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)
title [η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)
title_full [η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)
title_fullStr [η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)
title_full_unstemmed [η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)
title_short [η(5)-2,3-Bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(N,N,N′,N′-tetramethylethylenediamine)dysprosium(III)
title_sort [η(5)-2,3-bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(2−)]chlorido(n,n,n′,n′-tetramethylethylenediamine)dysprosium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961499/
https://www.ncbi.nlm.nih.gov/pubmed/21202486
http://dx.doi.org/10.1107/S1600536808013615
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