(2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate

The title compound, C(9)H(11)N(2)O(5) (+)·Cl(−)·H(2)O, was synthesized from (1S,2S)-2-amino-1-(4-nitro­phen­yl)propane-1,3-diol in four steps. As demonstrated by this work, no racemization occurs during this synthetic procedure. The crystal structure displays many inter­molecular hydrogen bonds betw...

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Detalles Bibliográficos
Autores principales: Gaumet, Vincent, Weber, Valérie, Zaitsev, Valery P., Madesclaire, Michel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961501/
https://www.ncbi.nlm.nih.gov/pubmed/21202530
http://dx.doi.org/10.1107/S1600536808012750
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author Gaumet, Vincent
Weber, Valérie
Zaitsev, Valery P.
Madesclaire, Michel
author_facet Gaumet, Vincent
Weber, Valérie
Zaitsev, Valery P.
Madesclaire, Michel
author_sort Gaumet, Vincent
collection PubMed
description The title compound, C(9)H(11)N(2)O(5) (+)·Cl(−)·H(2)O, was synthesized from (1S,2S)-2-amino-1-(4-nitro­phen­yl)propane-1,3-diol in four steps. As demonstrated by this work, no racemization occurs during this synthetic procedure. The crystal structure displays many inter­molecular hydrogen bonds between the acidic cation, chloride anions and the water mol­ecules, forming a three-dimensional network. An intra­molecular bond between the ammonium group and a hydroxyl O atom is also present.
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spelling pubmed-29615012010-12-30 (2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate Gaumet, Vincent Weber, Valérie Zaitsev, Valery P. Madesclaire, Michel Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(9)H(11)N(2)O(5) (+)·Cl(−)·H(2)O, was synthesized from (1S,2S)-2-amino-1-(4-nitro­phen­yl)propane-1,3-diol in four steps. As demonstrated by this work, no racemization occurs during this synthetic procedure. The crystal structure displays many inter­molecular hydrogen bonds between the acidic cation, chloride anions and the water mol­ecules, forming a three-dimensional network. An intra­molecular bond between the ammonium group and a hydroxyl O atom is also present. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961501/ /pubmed/21202530 http://dx.doi.org/10.1107/S1600536808012750 Text en © Gaumet et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gaumet, Vincent
Weber, Valérie
Zaitsev, Valery P.
Madesclaire, Michel
(2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
title (2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
title_full (2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
title_fullStr (2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
title_full_unstemmed (2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
title_short (2R,3S)-2-Ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
title_sort (2r,3s)-2-ammonio-3-hydr­oxy-3-(4-nitro­phen­yl)propanoic acid chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961501/
https://www.ncbi.nlm.nih.gov/pubmed/21202530
http://dx.doi.org/10.1107/S1600536808012750
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