Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)

The complete mol­ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(9)H(21)OP)(2)], is generated by crystallographic inversion symmetry, the Sn atom is located on a special position of site symmetry [Image: see text]. The Sn atom adopts an all-trans SnC(2)O(2)Cl(2) octa­hedral geometry. As a conse...

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Detalles Bibliográficos
Autores principales: Müller, Manuela, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961504/
https://www.ncbi.nlm.nih.gov/pubmed/21202490
http://dx.doi.org/10.1107/S1600536808013809
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author Müller, Manuela
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Müller, Manuela
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Müller, Manuela
collection PubMed
description The complete mol­ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(9)H(21)OP)(2)], is generated by crystallographic inversion symmetry, the Sn atom is located on a special position of site symmetry [Image: see text]. The Sn atom adopts an all-trans SnC(2)O(2)Cl(2) octa­hedral geometry. As a consequence of the bulky substituents at the O atom, the P—O—Sn bond angle is 163.9 (3)°.
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spelling pubmed-29615042010-12-30 Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV) Müller, Manuela Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(9)H(21)OP)(2)], is generated by crystallographic inversion symmetry, the Sn atom is located on a special position of site symmetry [Image: see text]. The Sn atom adopts an all-trans SnC(2)O(2)Cl(2) octa­hedral geometry. As a consequence of the bulky substituents at the O atom, the P—O—Sn bond angle is 163.9 (3)°. International Union of Crystallography 2008-05-10 /pmc/articles/PMC2961504/ /pubmed/21202490 http://dx.doi.org/10.1107/S1600536808013809 Text en © Müller et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Müller, Manuela
Lerner, Hans-Wolfram
Bolte, Michael
Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)
title Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)
title_full Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)
title_fullStr Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)
title_full_unstemmed Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)
title_short Dichloridobis(di-tert-butyl­methyl­phosphine oxide-κO)diphenyl­tin(IV)
title_sort dichloridobis(di-tert-butyl­methyl­phosphine oxide-κo)diphenyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961504/
https://www.ncbi.nlm.nih.gov/pubmed/21202490
http://dx.doi.org/10.1107/S1600536808013809
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AT boltemichael dichloridobisditertbutylmethylphosphineoxidekodiphenyltiniv

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