1,2-Bis(undecyl­sulfan­yl)benzene

In the title compound, C(28)H(50)S(2), the alkyl chains adopt a fully extended all-trans conformation and each of them is almost perfectly planar. One of the alkyl chains is coplanar with the benzene ring and the other is twisted out of the benzene ring plane; the C—C—S—C torsion angles are 176.4 (2...

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Detalles Bibliográficos
Autores principales: Tomiyama, Etsuko, Miyamura, Kazuo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961508/
https://www.ncbi.nlm.nih.gov/pubmed/21202630
http://dx.doi.org/10.1107/S1600536808014712
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author Tomiyama, Etsuko
Miyamura, Kazuo
author_facet Tomiyama, Etsuko
Miyamura, Kazuo
author_sort Tomiyama, Etsuko
collection PubMed
description In the title compound, C(28)H(50)S(2), the alkyl chains adopt a fully extended all-trans conformation and each of them is almost perfectly planar. One of the alkyl chains is coplanar with the benzene ring and the other is twisted out of the benzene ring plane; the C—C—S—C torsion angles are 176.4 (2) and 80.8 (3)°. In the crystal structure, an inter­molecular S⋯S inter­action [3.2123 (13) Å] links the mol­ecules into a centrosymmetric dimer; dimers are linked through weak C—H⋯π and C—H⋯S inter­actions, forming a column along the a axis.
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spelling pubmed-29615082010-12-30 1,2-Bis(undecyl­sulfan­yl)benzene Tomiyama, Etsuko Miyamura, Kazuo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(50)S(2), the alkyl chains adopt a fully extended all-trans conformation and each of them is almost perfectly planar. One of the alkyl chains is coplanar with the benzene ring and the other is twisted out of the benzene ring plane; the C—C—S—C torsion angles are 176.4 (2) and 80.8 (3)°. In the crystal structure, an inter­molecular S⋯S inter­action [3.2123 (13) Å] links the mol­ecules into a centrosymmetric dimer; dimers are linked through weak C—H⋯π and C—H⋯S inter­actions, forming a column along the a axis. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961508/ /pubmed/21202630 http://dx.doi.org/10.1107/S1600536808014712 Text en © Tomiyama and Miyamura 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tomiyama, Etsuko
Miyamura, Kazuo
1,2-Bis(undecyl­sulfan­yl)benzene
title 1,2-Bis(undecyl­sulfan­yl)benzene
title_full 1,2-Bis(undecyl­sulfan­yl)benzene
title_fullStr 1,2-Bis(undecyl­sulfan­yl)benzene
title_full_unstemmed 1,2-Bis(undecyl­sulfan­yl)benzene
title_short 1,2-Bis(undecyl­sulfan­yl)benzene
title_sort 1,2-bis(undecyl­sulfan­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961508/
https://www.ncbi.nlm.nih.gov/pubmed/21202630
http://dx.doi.org/10.1107/S1600536808014712
work_keys_str_mv AT tomiyamaetsuko 12bisundecylsulfanylbenzene
AT miyamurakazuo 12bisundecylsulfanylbenzene

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