Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited

We present a new low-temperature refinement of disodium zinc bis­(sulfate) tetra­hydrate {systematic name: poly[tetra-μ-aqua-di-μ-sulfato-zinc(II)disodium(I)]}, [Na(2)Zn(SO(4))(2)(H(2)O)(4)](n) or Zn astrakanite, which is an upgrade of previously reported data [Bukin & Nozik (1974 ▶). Zh. Strukt...

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Autores principales: Díaz de Vivar, M. Enriqueta, Baggio, Sergio, Ibáñez, Andrés, Baggio, Ricardo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961512/
https://www.ncbi.nlm.nih.gov/pubmed/21202433
http://dx.doi.org/10.1107/S1600536808009719
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author Díaz de Vivar, M. Enriqueta
Baggio, Sergio
Ibáñez, Andrés
Baggio, Ricardo
author_facet Díaz de Vivar, M. Enriqueta
Baggio, Sergio
Ibáñez, Andrés
Baggio, Ricardo
author_sort Díaz de Vivar, M. Enriqueta
collection PubMed
description We present a new low-temperature refinement of disodium zinc bis­(sulfate) tetra­hydrate {systematic name: poly[tetra-μ-aqua-di-μ-sulfato-zinc(II)disodium(I)]}, [Na(2)Zn(SO(4))(2)(H(2)O)(4)](n) or Zn astrakanite, which is an upgrade of previously reported data [Bukin & Nozik (1974 ▶). Zh. Strukt. Khim. 15, 712–716]. The compound is part of an isostructural family containing the Mg (the original astrakanite mineral), Co and Ni species. The very regular ZnO(aqua)(4)O(sulfate)(2) octa­hedra lie on centres of symmetry, while the rather distorted NaO(aqua)(2)O(sulfate)(4) octa­hedra appear at general positions, linked into a three-dimensional network by the bridging water mol­ecules and the fully coordinated sulfate groups.
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spelling pubmed-29615122010-12-30 Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited Díaz de Vivar, M. Enriqueta Baggio, Sergio Ibáñez, Andrés Baggio, Ricardo Acta Crystallogr Sect E Struct Rep Online Inorganic Papers We present a new low-temperature refinement of disodium zinc bis­(sulfate) tetra­hydrate {systematic name: poly[tetra-μ-aqua-di-μ-sulfato-zinc(II)disodium(I)]}, [Na(2)Zn(SO(4))(2)(H(2)O)(4)](n) or Zn astrakanite, which is an upgrade of previously reported data [Bukin & Nozik (1974 ▶). Zh. Strukt. Khim. 15, 712–716]. The compound is part of an isostructural family containing the Mg (the original astrakanite mineral), Co and Ni species. The very regular ZnO(aqua)(4)O(sulfate)(2) octa­hedra lie on centres of symmetry, while the rather distorted NaO(aqua)(2)O(sulfate)(4) octa­hedra appear at general positions, linked into a three-dimensional network by the bridging water mol­ecules and the fully coordinated sulfate groups. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961512/ /pubmed/21202433 http://dx.doi.org/10.1107/S1600536808009719 Text en © Díaz de Vivar et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Díaz de Vivar, M. Enriqueta
Baggio, Sergio
Ibáñez, Andrés
Baggio, Ricardo
Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
title Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
title_full Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
title_fullStr Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
title_full_unstemmed Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
title_short Disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
title_sort disodium zinc bis­(sulfate) tetra­hydrate (zinc astrakanite) revisited
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961512/
https://www.ncbi.nlm.nih.gov/pubmed/21202433
http://dx.doi.org/10.1107/S1600536808009719
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AT ibanezandres disodiumzincbissulfatetetrahydratezincastrakaniterevisited
AT baggioricardo disodiumzincbissulfatetetrahydratezincastrakaniterevisited

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