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2-(4-Iodophenyl)-5,7-dimethyl-3-methylsulfinyl-1-benzofuran
The title compound, C(17)H(15)IO(2)S, was prepared by the oxidation of 2-(4-iodophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran using 3-chloroperoxybenzoic acid. The 4-iodophenyl ring makes a dihedral angle of 26.0 (1)° with the plane of the benzofuran fragment, and the O atom and the methy...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961519/ https://www.ncbi.nlm.nih.gov/pubmed/21202603 http://dx.doi.org/10.1107/S1600536808014104 |
Sumario: | The title compound, C(17)H(15)IO(2)S, was prepared by the oxidation of 2-(4-iodophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran using 3-chloroperoxybenzoic acid. The 4-iodophenyl ring makes a dihedral angle of 26.0 (1)° with the plane of the benzofuran fragment, and the O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of this plane. The crystal structure is stabilized by inter- and intramolecular C—H⋯O hydrogen bonds, and by an I⋯O halogen bond with an I⋯O distance of 3.145 (2) Å and a nearly linear C—I⋯O angle of 164.01 (9)°. |
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