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2-(4-Iodo­phen­yl)-5,7-dimethyl-3-methyl­sulfinyl-1-benzofuran

The title compound, C(17)H(15)IO(2)S, was prepared by the oxidation of 2-(4-iodo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran using 3-chloro­peroxy­benzoic acid. The 4-iodo­phenyl ring makes a dihedral angle of 26.0 (1)° with the plane of the benzofuran fragment, and the O atom and the methy...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961519/
https://www.ncbi.nlm.nih.gov/pubmed/21202603
http://dx.doi.org/10.1107/S1600536808014104
Descripción
Sumario:The title compound, C(17)H(15)IO(2)S, was prepared by the oxidation of 2-(4-iodo­phen­yl)-5,7-dimethyl-3-methyl­sulfanyl-1-benzofuran using 3-chloro­peroxy­benzoic acid. The 4-iodo­phenyl ring makes a dihedral angle of 26.0 (1)° with the plane of the benzofuran fragment, and the O atom and the methyl group of the methyl­sulfinyl substituent lie on opposite sides of this plane. The crystal structure is stabilized by inter- and intra­molecular C—H⋯O hydrogen bonds, and by an I⋯O halogen bond with an I⋯O distance of 3.145 (2) Å and a nearly linear C—I⋯O angle of 164.01 (9)°.