(4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione

In the title compound, C(37)H(27)Cl(2)NO(2), the 3,4-dichloro­phenyl ring makes a dihedral angle of 46.66 (6)° with the phenyl ring. The mol­ecular structure is stabilized by weak intra­molecular C—H⋯O inter­actions and the crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions....

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Detalles Bibliográficos
Autores principales: Murugan, R., Gunasekaran, B., Narayanan, S. Sriman, Manivannan, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961525/
https://www.ncbi.nlm.nih.gov/pubmed/21202604
http://dx.doi.org/10.1107/S1600536808013846
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author Murugan, R.
Gunasekaran, B.
Narayanan, S. Sriman
Manivannan, V.
author_facet Murugan, R.
Gunasekaran, B.
Narayanan, S. Sriman
Manivannan, V.
author_sort Murugan, R.
collection PubMed
description In the title compound, C(37)H(27)Cl(2)NO(2), the 3,4-dichloro­phenyl ring makes a dihedral angle of 46.66 (6)° with the phenyl ring. The mol­ecular structure is stabilized by weak intra­molecular C—H⋯O inter­actions and the crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions. The C–C–C–C–C five-membered ring is planar, while the C–C–C–C–N five-membered ring adopts a half-chair conformation.
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spelling pubmed-29615252010-12-30 (4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione Murugan, R. Gunasekaran, B. Narayanan, S. Sriman Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(37)H(27)Cl(2)NO(2), the 3,4-dichloro­phenyl ring makes a dihedral angle of 46.66 (6)° with the phenyl ring. The mol­ecular structure is stabilized by weak intra­molecular C—H⋯O inter­actions and the crystal structure is stabilized by weak inter­molecular C—H⋯O inter­actions. The C–C–C–C–C five-membered ring is planar, while the C–C–C–C–N five-membered ring adopts a half-chair conformation. International Union of Crystallography 2008-05-17 /pmc/articles/PMC2961525/ /pubmed/21202604 http://dx.doi.org/10.1107/S1600536808013846 Text en © Murugan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Murugan, R.
Gunasekaran, B.
Narayanan, S. Sriman
Manivannan, V.
(4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione
title (4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione
title_full (4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione
title_fullStr (4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione
title_full_unstemmed (4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione
title_short (4S)-4-(3,4-Dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2H,1′′H)-dione
title_sort (4s)-4-(3,4-dichloro­phen­yl)-1′-methyl-4′-phenyl-3,4-dihydronaphthalene-2-spiro-3′-pyrrolidine-2′-spiro-1′′-acenaphthyl­ene-1,2′′(2h,1′′h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961525/
https://www.ncbi.nlm.nih.gov/pubmed/21202604
http://dx.doi.org/10.1107/S1600536808013846
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AT narayananssriman 4s434dichlorophenyl1methyl4phenyl34dihydronaphthalene2spiro3pyrrolidine2spiro1acenaphthylene122h1hdione
AT manivannanv 4s434dichlorophenyl1methyl4phenyl34dihydronaphthalene2spiro3pyrrolidine2spiro1acenaphthylene122h1hdione

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