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Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate]
In the title complex, {[Ag(2)(CF(3)O(3)S)(2)(C(30)H(20)N(6))]·C(6)H(6)}(n), the two independent Ag(I) ions are each coordinated by two N atoms and one O atom in a ‘T-shaped’ geometry. In the crystal structure, 1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane ligands act as bridging liga...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961533/ https://www.ncbi.nlm.nih.gov/pubmed/21202474 http://dx.doi.org/10.1107/S1600536808012853 |
| _version_ | 1782189005458112512 |
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| author | Li, Hong Liang |
| author_facet | Li, Hong Liang |
| author_sort | Li, Hong Liang |
| collection | PubMed |
| description | In the title complex, {[Ag(2)(CF(3)O(3)S)(2)(C(30)H(20)N(6))]·C(6)H(6)}(n), the two independent Ag(I) ions are each coordinated by two N atoms and one O atom in a ‘T-shaped’ geometry. In the crystal structure, 1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane ligands act as bridging ligands and each coordinates to four Ag(I) ions, resulting in a one-dimensional chain structure. The crystal structure is stabilized by weak intermolecular C—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2961533 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29615332010-12-30 Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] Li, Hong Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Ag(2)(CF(3)O(3)S)(2)(C(30)H(20)N(6))]·C(6)H(6)}(n), the two independent Ag(I) ions are each coordinated by two N atoms and one O atom in a ‘T-shaped’ geometry. In the crystal structure, 1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane ligands act as bridging ligands and each coordinates to four Ag(I) ions, resulting in a one-dimensional chain structure. The crystal structure is stabilized by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961533/ /pubmed/21202474 http://dx.doi.org/10.1107/S1600536808012853 Text en © Hong Liang Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, Hong Liang Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] |
| title | Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] |
| title_full | Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] |
| title_fullStr | Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] |
| title_full_unstemmed | Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] |
| title_short | Poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(I)] benzene solvate] |
| title_sort | poly[[{μ(4)-1,2-bis[(3-cyanobenzylidene)hydrazono]-1,2-diphenylethane}bis(trifluoromethanesulfonato)disilver(i)] benzene solvate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961533/ https://www.ncbi.nlm.nih.gov/pubmed/21202474 http://dx.doi.org/10.1107/S1600536808012853 |
| work_keys_str_mv | AT lihongliang polym412bis3cyanobenzylidenehydrazono12diphenylethanebistrifluoromethanesulfonatodisilveribenzenesolvate |