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Bis[4-(2-hydroxy-3-methoxybenzylideneamino)phenyl] ether
The title compound, C(28)H(24)N(2)O(5), a flexible Schiff base ligand, was prepared in high yield by a Schiff base condensation of 3-methoxysalicylaldehyde and bis(4-aminophenyl) ether in methanol. The molecule lies on a twofold rotation axis, and each half exhibits an imine E configuration and...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961534/ https://www.ncbi.nlm.nih.gov/pubmed/21202654 http://dx.doi.org/10.1107/S1600536808014980 |
Sumario: | The title compound, C(28)H(24)N(2)O(5), a flexible Schiff base ligand, was prepared in high yield by a Schiff base condensation of 3-methoxysalicylaldehyde and bis(4-aminophenyl) ether in methanol. The molecule lies on a twofold rotation axis, and each half exhibits an imine E configuration and an O—H⋯N hydrogen bond. The dihedral angle between the two benzene rings attached to the central O atom is 69.22 (6)°, and that between each of these rings and the other benzene ring in the same half of the molecule is 24.29 (11)°, illustrating the degree of twisting of the flexible molecule. |
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