8-Bromo­naphthalen-1-amine

The title compound, C(10)H(8)BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compoun...

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Detalles Bibliográficos
Autores principales: Fuller, Amy L., Knight, Fergus R., Slawin, Alexandra M. Z., Woollins, J. Derek
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961535/
https://www.ncbi.nlm.nih.gov/pubmed/21202706
http://dx.doi.org/10.1107/S1600536808012580
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author Fuller, Amy L.
Knight, Fergus R.
Slawin, Alexandra M. Z.
Woollins, J. Derek
author_facet Fuller, Amy L.
Knight, Fergus R.
Slawin, Alexandra M. Z.
Woollins, J. Derek
author_sort Fuller, Amy L.
collection PubMed
description The title compound, C(10)H(8)BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compound exhibits less strain between the 1 and 8 substituents. Additionally, the NH protons form both intra- and inter­molecular hydrogen bonds. The naphthalene units are arranged in a herring-bone stacking motif.
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spelling pubmed-29615352010-12-30 8-Bromo­naphthalen-1-amine Fuller, Amy L. Knight, Fergus R. Slawin, Alexandra M. Z. Woollins, J. Derek Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(8)BrN, was obtained by slow addition of sodium azide to 8-bromo-1-naphthoic acid, followed by addition of aqueous ammonia. The crude product was crystallized from petroleum ether to give pink crystals. Compared to other 1,8-disubstituted naphthalene compounds, this compound exhibits less strain between the 1 and 8 substituents. Additionally, the NH protons form both intra- and inter­molecular hydrogen bonds. The naphthalene units are arranged in a herring-bone stacking motif. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961535/ /pubmed/21202706 http://dx.doi.org/10.1107/S1600536808012580 Text en © Fuller et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fuller, Amy L.
Knight, Fergus R.
Slawin, Alexandra M. Z.
Woollins, J. Derek
8-Bromo­naphthalen-1-amine
title 8-Bromo­naphthalen-1-amine
title_full 8-Bromo­naphthalen-1-amine
title_fullStr 8-Bromo­naphthalen-1-amine
title_full_unstemmed 8-Bromo­naphthalen-1-amine
title_short 8-Bromo­naphthalen-1-amine
title_sort 8-bromo­naphthalen-1-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961535/
https://www.ncbi.nlm.nih.gov/pubmed/21202706
http://dx.doi.org/10.1107/S1600536808012580
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