Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)

In the title compound, [RuCl(2)(C(16)H(32)P(2))(2)], the Ru(II) ion is situated on a twofold rotation axis, so the asymmetric unit contains one half-mol­ecule. The slightly distorted octa­hedral environment of the Ru center is formed by four P atoms [Ru—P = 2.4417 (6) and 2.4544 (6) Å] from two diff...

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Detalles Bibliográficos
Autores principales: Wang, Chubei, Tao, Haiyan, Ji, Baoming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961537/
https://www.ncbi.nlm.nih.gov/pubmed/21202447
http://dx.doi.org/10.1107/S1600536808008301
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author Wang, Chubei
Tao, Haiyan
Ji, Baoming
author_facet Wang, Chubei
Tao, Haiyan
Ji, Baoming
author_sort Wang, Chubei
collection PubMed
description In the title compound, [RuCl(2)(C(16)H(32)P(2))(2)], the Ru(II) ion is situated on a twofold rotation axis, so the asymmetric unit contains one half-mol­ecule. The slightly distorted octa­hedral environment of the Ru center is formed by four P atoms [Ru—P = 2.4417 (6) and 2.4544 (6) Å] from two different (1S,1S′,2R,2R′)-TangPhos ligands [(1S,1S′,2R,2R′)-TangPhos = (1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane] and two Cl atoms [Ru—Cl = 2.4267 (5) Å].
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spelling pubmed-29615372010-12-30 Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II) Wang, Chubei Tao, Haiyan Ji, Baoming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RuCl(2)(C(16)H(32)P(2))(2)], the Ru(II) ion is situated on a twofold rotation axis, so the asymmetric unit contains one half-mol­ecule. The slightly distorted octa­hedral environment of the Ru center is formed by four P atoms [Ru—P = 2.4417 (6) and 2.4544 (6) Å] from two different (1S,1S′,2R,2R′)-TangPhos ligands [(1S,1S′,2R,2R′)-TangPhos = (1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane] and two Cl atoms [Ru—Cl = 2.4267 (5) Å]. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961537/ /pubmed/21202447 http://dx.doi.org/10.1107/S1600536808008301 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chubei
Tao, Haiyan
Ji, Baoming
Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)
title Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)
title_full Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)
title_fullStr Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)
title_full_unstemmed Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)
title_short Dichloridobis[(1S,1S′,2R,2R′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) P,P′]ruthenium(II)
title_sort dichloridobis[(1s,1s′,2r,2r′)-(+)-1,1′-di-tert-butyl-2,2′-diphospho­lane-κ(2) p,p′]ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961537/
https://www.ncbi.nlm.nih.gov/pubmed/21202447
http://dx.doi.org/10.1107/S1600536808008301
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AT taohaiyan dichloridobis1s1s2r2r11ditertbutyl22diphospholanek2pprutheniumii
AT jibaoming dichloridobis1s1s2r2r11ditertbutyl22diphospholanek2pprutheniumii

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