Cargando…
1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate
The asymmetric unit of the title compound, (C(12)H(28)N(2)O(4))[AuCl(4)](2)·2H(2)O, contains one half-cation, one anion and one water molecule; the cation is centrosymmetric. The Au ion has a square-planar coordination. In the crystal structure, intramolecular N—H⋯O and O—H⋯O, and intermolecular...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961538/ https://www.ncbi.nlm.nih.gov/pubmed/21202520 http://dx.doi.org/10.1107/S1600536808015353 |
_version_ | 1782189006593720320 |
---|---|
author | Hojjat Kashani, Leila Yousefi, Mohammad Amani, Vahid Khavasi, Hamid Reza |
author_facet | Hojjat Kashani, Leila Yousefi, Mohammad Amani, Vahid Khavasi, Hamid Reza |
author_sort | Hojjat Kashani, Leila |
collection | PubMed |
description | The asymmetric unit of the title compound, (C(12)H(28)N(2)O(4))[AuCl(4)](2)·2H(2)O, contains one half-cation, one anion and one water molecule; the cation is centrosymmetric. The Au ion has a square-planar coordination. In the crystal structure, intramolecular N—H⋯O and O—H⋯O, and intermolecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the ions and water molecules, forming a supramolecular structure. |
format | Text |
id | pubmed-2961538 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29615382010-12-30 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate Hojjat Kashani, Leila Yousefi, Mohammad Amani, Vahid Khavasi, Hamid Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(12)H(28)N(2)O(4))[AuCl(4)](2)·2H(2)O, contains one half-cation, one anion and one water molecule; the cation is centrosymmetric. The Au ion has a square-planar coordination. In the crystal structure, intramolecular N—H⋯O and O—H⋯O, and intermolecular N—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds link the ions and water molecules, forming a supramolecular structure. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961538/ /pubmed/21202520 http://dx.doi.org/10.1107/S1600536808015353 Text en © Hojjat Kashani et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hojjat Kashani, Leila Yousefi, Mohammad Amani, Vahid Khavasi, Hamid Reza 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate |
title | 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate |
title_full | 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate |
title_fullStr | 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate |
title_full_unstemmed | 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate |
title_short | 1,4,10,13-Tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(III)] dihydrate |
title_sort | 1,4,10,13-tetraoxa-7,16-diazoniacyclooctadecane bis[tetrachloridoaurate(iii)] dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961538/ https://www.ncbi.nlm.nih.gov/pubmed/21202520 http://dx.doi.org/10.1107/S1600536808015353 |
work_keys_str_mv | AT hojjatkashanileila 141013tetraoxa716diazoniacyclooctadecanebistetrachloridoaurateiiidihydrate AT yousefimohammad 141013tetraoxa716diazoniacyclooctadecanebistetrachloridoaurateiiidihydrate AT amanivahid 141013tetraoxa716diazoniacyclooctadecanebistetrachloridoaurateiiidihydrate AT khavasihamidreza 141013tetraoxa716diazoniacyclooctadecanebistetrachloridoaurateiiidihydrate |