Bis[1,5-bis­(1H-indol-3-ylmethyl­ene)thio­carbazonato-κ(2) N,S]nickel(II) dimethyl sulfoxide disolvate

The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites inter­act with dimethyl sulfo...

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Detalles Bibliográficos
Autores principales: Rizal, Mohd. Razali, Ali, Hapipah M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961539/
https://www.ncbi.nlm.nih.gov/pubmed/21202448
http://dx.doi.org/10.1107/S1600536808011975
Descripción
Sumario:The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites inter­act with dimethyl sulfoxide mol­ecules to furnish a layer motif.

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