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Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2) N,S]nickel(II) dimethyl sulfoxide disolvate
The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites interact with dimethyl sulfo...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961539/ https://www.ncbi.nlm.nih.gov/pubmed/21202448 http://dx.doi.org/10.1107/S1600536808011975 |
| _version_ | 1782189006834892800 |
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| author | Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng |
| author_facet | Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng |
| author_sort | Rizal, Mohd. Razali |
| collection | PubMed |
| description | The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites interact with dimethyl sulfoxide molecules to furnish a layer motif. |
| format | Text |
| id | pubmed-2961539 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29615392010-12-30 Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2) N,S]nickel(II) dimethyl sulfoxide disolvate Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Ni atom in the crystal structure of the centrosymmetric title compound, [Ni(C(19)H(15)N(6)S)(2)]·2C(2)H(6)OS, is N,S-chelated by the deprotonated Schiff bases in a square-planar geometry. The –CH=N—N=C(S)—NH—N=CH– frament is planar. The two indolyl –NH (donor) sites interact with dimethyl sulfoxide molecules to furnish a layer motif. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961539/ /pubmed/21202448 http://dx.doi.org/10.1107/S1600536808011975 Text en © Rizal et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Rizal, Mohd. Razali Ali, Hapipah M. Ng, Seik Weng Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2) N,S]nickel(II) dimethyl sulfoxide disolvate |
| title | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2)
N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_full | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2)
N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_fullStr | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2)
N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_full_unstemmed | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2)
N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_short | Bis[1,5-bis(1H-indol-3-ylmethylene)thiocarbazonato-κ(2)
N,S]nickel(II) dimethyl sulfoxide disolvate |
| title_sort | bis[1,5-bis(1h-indol-3-ylmethylene)thiocarbazonato-κ(2)
n,s]nickel(ii) dimethyl sulfoxide disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961539/ https://www.ncbi.nlm.nih.gov/pubmed/21202448 http://dx.doi.org/10.1107/S1600536808011975 |
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