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Bis(1H-benzimidazole-κN (3))bis(4-methylbenzoato-κ(2) O,O′)copper(II)
In the title mononuclear complex, [Cu(C(8)H(7)O(2))(2)(C(7)H(6)N(2))(2)], the Cu(II) atom lies on an inversion centre and is coordinated by two O atoms of two monodentate 4-methylbenzoate ligands and two N atoms of two benzimidazole ligands in a square-planar geometry. The molecules are linked int...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961541/ https://www.ncbi.nlm.nih.gov/pubmed/21202457 http://dx.doi.org/10.1107/S1600536808012440 |
| _version_ | 1782189007295217664 |
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| author | Song, Wen-Dong Huang, Xiang-Hu Wang, Hui |
| author_facet | Song, Wen-Dong Huang, Xiang-Hu Wang, Hui |
| author_sort | Song, Wen-Dong |
| collection | PubMed |
| description | In the title mononuclear complex, [Cu(C(8)H(7)O(2))(2)(C(7)H(6)N(2))(2)], the Cu(II) atom lies on an inversion centre and is coordinated by two O atoms of two monodentate 4-methylbenzoate ligands and two N atoms of two benzimidazole ligands in a square-planar geometry. The molecules are linked into chains running parallel to the b axis by intermolecular N—H⋯O hydrogen bonds and by π–π stacking interactions [centroid–centroid distance = 3.669 (2) Å] involving centrosymmetrically related imidazole rings. |
| format | Text |
| id | pubmed-2961541 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29615412010-12-30 Bis(1H-benzimidazole-κN (3))bis(4-methylbenzoato-κ(2) O,O′)copper(II) Song, Wen-Dong Huang, Xiang-Hu Wang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Cu(C(8)H(7)O(2))(2)(C(7)H(6)N(2))(2)], the Cu(II) atom lies on an inversion centre and is coordinated by two O atoms of two monodentate 4-methylbenzoate ligands and two N atoms of two benzimidazole ligands in a square-planar geometry. The molecules are linked into chains running parallel to the b axis by intermolecular N—H⋯O hydrogen bonds and by π–π stacking interactions [centroid–centroid distance = 3.669 (2) Å] involving centrosymmetrically related imidazole rings. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961541/ /pubmed/21202457 http://dx.doi.org/10.1107/S1600536808012440 Text en © Song et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Song, Wen-Dong Huang, Xiang-Hu Wang, Hui Bis(1H-benzimidazole-κN (3))bis(4-methylbenzoato-κ(2) O,O′)copper(II) |
| title | Bis(1H-benzimidazole-κN
(3))bis(4-methylbenzoato-κ(2)
O,O′)copper(II) |
| title_full | Bis(1H-benzimidazole-κN
(3))bis(4-methylbenzoato-κ(2)
O,O′)copper(II) |
| title_fullStr | Bis(1H-benzimidazole-κN
(3))bis(4-methylbenzoato-κ(2)
O,O′)copper(II) |
| title_full_unstemmed | Bis(1H-benzimidazole-κN
(3))bis(4-methylbenzoato-κ(2)
O,O′)copper(II) |
| title_short | Bis(1H-benzimidazole-κN
(3))bis(4-methylbenzoato-κ(2)
O,O′)copper(II) |
| title_sort | bis(1h-benzimidazole-κn
(3))bis(4-methylbenzoato-κ(2)
o,o′)copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961541/ https://www.ncbi.nlm.nih.gov/pubmed/21202457 http://dx.doi.org/10.1107/S1600536808012440 |
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