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(E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone
Crystals of the title compound, C(11)H(9)N(5)O(4)S, were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and methyl 1,3-thiazol-2-yl ketone. Excluding two methyl H atoms, the molecule displays a planar structure, the dihedral angle between the terminal thiazole and benzene r...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961542/ https://www.ncbi.nlm.nih.gov/pubmed/21202664 http://dx.doi.org/10.1107/S1600536808015298 |
Sumario: | Crystals of the title compound, C(11)H(9)N(5)O(4)S, were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and methyl 1,3-thiazol-2-yl ketone. Excluding two methyl H atoms, the molecule displays a planar structure, the dihedral angle between the terminal thiazole and benzene rings being 1.82 (8)°. The imino group links with adjacent nitro and thiazole groups by intramolecular bifurcated hydrogen bonding. The centroid–centroid separation of 3.7273 (11) Å between nearly parallel benzene and thiazole rings of adjacent molecules indicates the existence of π–π stacking in the crystal structure. Weak intermolecular C—H⋯O hydrogen bonding is also observed. |
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