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(E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone
Crystals of the title compound, C(11)H(9)N(5)O(4)S, were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and methyl 1,3-thiazol-2-yl ketone. Excluding two methyl H atoms, the molecule displays a planar structure, the dihedral angle between the terminal thiazole and benzene r...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961542/ https://www.ncbi.nlm.nih.gov/pubmed/21202664 http://dx.doi.org/10.1107/S1600536808015298 |
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author | Shan, Shang Tian, Yu-Liang Wang, Shan-Heng Wang, Wen-Long Xu, Ying-Li |
author_facet | Shan, Shang Tian, Yu-Liang Wang, Shan-Heng Wang, Wen-Long Xu, Ying-Li |
author_sort | Shan, Shang |
collection | PubMed |
description | Crystals of the title compound, C(11)H(9)N(5)O(4)S, were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and methyl 1,3-thiazol-2-yl ketone. Excluding two methyl H atoms, the molecule displays a planar structure, the dihedral angle between the terminal thiazole and benzene rings being 1.82 (8)°. The imino group links with adjacent nitro and thiazole groups by intramolecular bifurcated hydrogen bonding. The centroid–centroid separation of 3.7273 (11) Å between nearly parallel benzene and thiazole rings of adjacent molecules indicates the existence of π–π stacking in the crystal structure. Weak intermolecular C—H⋯O hydrogen bonding is also observed. |
format | Text |
id | pubmed-2961542 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29615422010-12-30 (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone Shan, Shang Tian, Yu-Liang Wang, Shan-Heng Wang, Wen-Long Xu, Ying-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(11)H(9)N(5)O(4)S, were obtained from a condensation reaction of 2,4-dinitrophenylhydrazine and methyl 1,3-thiazol-2-yl ketone. Excluding two methyl H atoms, the molecule displays a planar structure, the dihedral angle between the terminal thiazole and benzene rings being 1.82 (8)°. The imino group links with adjacent nitro and thiazole groups by intramolecular bifurcated hydrogen bonding. The centroid–centroid separation of 3.7273 (11) Å between nearly parallel benzene and thiazole rings of adjacent molecules indicates the existence of π–π stacking in the crystal structure. Weak intermolecular C—H⋯O hydrogen bonding is also observed. International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961542/ /pubmed/21202664 http://dx.doi.org/10.1107/S1600536808015298 Text en © Shan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Shan, Shang Tian, Yu-Liang Wang, Shan-Heng Wang, Wen-Long Xu, Ying-Li (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
title | (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
title_full | (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
title_fullStr | (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
title_full_unstemmed | (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
title_short | (E)-Methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
title_sort | (e)-methyl 1,3-thiazol-2-yl ketone 2,4-dinitrophenylhydrazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961542/ https://www.ncbi.nlm.nih.gov/pubmed/21202664 http://dx.doi.org/10.1107/S1600536808015298 |
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