Dimethyl 2-(methyl­amino­methyl­ene)malonate

In the title compound, C(7)H(11)NO(4), which is an example of a push–pull alkene, a network of N—H⋯O and C—H⋯O inter­actions helps to establish the crystal structure. The investigated crystal turned out to be a non-merohedral twin with a ratio of twin components of 0.442 (3):0.558 (3). Two pairs of...

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Detalles Bibliográficos
Autores principales: Gróf, Martin, Kožíšek, Jozef, Milata, Viktor, Gatial, Anton
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961545/
https://www.ncbi.nlm.nih.gov/pubmed/21202643
http://dx.doi.org/10.1107/S1600536808014773
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author Gróf, Martin
Kožíšek, Jozef
Milata, Viktor
Gatial, Anton
author_facet Gróf, Martin
Kožíšek, Jozef
Milata, Viktor
Gatial, Anton
author_sort Gróf, Martin
collection PubMed
description In the title compound, C(7)H(11)NO(4), which is an example of a push–pull alkene, a network of N—H⋯O and C—H⋯O inter­actions helps to establish the crystal structure. The investigated crystal turned out to be a non-merohedral twin with a ratio of twin components of 0.442 (3):0.558 (3). Two pairs of independent mol­ecules (Z′ = 4) are linked by inter­molecular N—H⋯O hydrogen bonds, forming independent chains; the chains are connected via inter­molecular C—H⋯O contacts, building a three-dimensional network.
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spelling pubmed-29615452010-12-30 Dimethyl 2-(methyl­amino­methyl­ene)malonate Gróf, Martin Kožíšek, Jozef Milata, Viktor Gatial, Anton Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(11)NO(4), which is an example of a push–pull alkene, a network of N—H⋯O and C—H⋯O inter­actions helps to establish the crystal structure. The investigated crystal turned out to be a non-merohedral twin with a ratio of twin components of 0.442 (3):0.558 (3). Two pairs of independent mol­ecules (Z′ = 4) are linked by inter­molecular N—H⋯O hydrogen bonds, forming independent chains; the chains are connected via inter­molecular C—H⋯O contacts, building a three-dimensional network. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961545/ /pubmed/21202643 http://dx.doi.org/10.1107/S1600536808014773 Text en © Gróf et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gróf, Martin
Kožíšek, Jozef
Milata, Viktor
Gatial, Anton
Dimethyl 2-(methyl­amino­methyl­ene)malonate
title Dimethyl 2-(methyl­amino­methyl­ene)malonate
title_full Dimethyl 2-(methyl­amino­methyl­ene)malonate
title_fullStr Dimethyl 2-(methyl­amino­methyl­ene)malonate
title_full_unstemmed Dimethyl 2-(methyl­amino­methyl­ene)malonate
title_short Dimethyl 2-(methyl­amino­methyl­ene)malonate
title_sort dimethyl 2-(methyl­amino­methyl­ene)malonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961545/
https://www.ncbi.nlm.nih.gov/pubmed/21202643
http://dx.doi.org/10.1107/S1600536808014773
work_keys_str_mv AT grofmartin dimethyl2methylaminomethylenemalonate
AT kozisekjozef dimethyl2methylaminomethylenemalonate
AT milataviktor dimethyl2methylaminomethylenemalonate
AT gatialanton dimethyl2methylaminomethylenemalonate

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