1-De­oxy-d-arabinitol

Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de­oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de­oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol­ecules running par...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Cruz, Filipa P., Booth, Kathrine V., Fleet, George W. J., Izumori, Ken, Yu, Chu-Yi, Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961547/
https://www.ncbi.nlm.nih.gov/pubmed/21202536
http://dx.doi.org/10.1107/S1600536808012555
Descripción
Sumario:Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de­oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de­oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol­ecules running parallel to the c axis which are further linked together by hydrogen bonds. Each mol­ecule is a donor and an acceptor for four hydrogen bonds.

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