1-De­oxy-d-arabinitol

Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de­oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de­oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol­ecules running par...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Cruz, Filipa P., Booth, Kathrine V., Fleet, George W. J., Izumori, Ken, Yu, Chu-Yi, Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961547/
https://www.ncbi.nlm.nih.gov/pubmed/21202536
http://dx.doi.org/10.1107/S1600536808012555
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author Jenkinson, Sarah F.
Cruz, Filipa P.
Booth, Kathrine V.
Fleet, George W. J.
Izumori, Ken
Yu, Chu-Yi
Watkin, David J.
author_facet Jenkinson, Sarah F.
Cruz, Filipa P.
Booth, Kathrine V.
Fleet, George W. J.
Izumori, Ken
Yu, Chu-Yi
Watkin, David J.
author_sort Jenkinson, Sarah F.
collection PubMed
description Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de­oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de­oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol­ecules running parallel to the c axis which are further linked together by hydrogen bonds. Each mol­ecule is a donor and an acceptor for four hydrogen bonds.
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spelling pubmed-29615472010-12-30 1-De­oxy-d-arabinitol Jenkinson, Sarah F. Cruz, Filipa P. Booth, Kathrine V. Fleet, George W. J. Izumori, Ken Yu, Chu-Yi Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers Addition of methyl lithium to d-erythrono-1,4-lactone followed by acid deprotection was shown, by X-ray crystallography, to give 1-de­oxy-d-arabinitol, C(5)H(12)O(4), rather than 1-de­oxy-d-ribitol as the major product. The crystal structure exists as hydrogen-bonded chains of mol­ecules running parallel to the c axis which are further linked together by hydrogen bonds. Each mol­ecule is a donor and an acceptor for four hydrogen bonds. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961547/ /pubmed/21202536 http://dx.doi.org/10.1107/S1600536808012555 Text en © Jenkinson et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jenkinson, Sarah F.
Cruz, Filipa P.
Booth, Kathrine V.
Fleet, George W. J.
Izumori, Ken
Yu, Chu-Yi
Watkin, David J.
1-De­oxy-d-arabinitol
title 1-De­oxy-d-arabinitol
title_full 1-De­oxy-d-arabinitol
title_fullStr 1-De­oxy-d-arabinitol
title_full_unstemmed 1-De­oxy-d-arabinitol
title_short 1-De­oxy-d-arabinitol
title_sort 1-de­oxy-d-arabinitol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961547/
https://www.ncbi.nlm.nih.gov/pubmed/21202536
http://dx.doi.org/10.1107/S1600536808012555
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AT cruzfilipap 1deoxydarabinitol
AT boothkathrinev 1deoxydarabinitol
AT fleetgeorgewj 1deoxydarabinitol
AT izumoriken 1deoxydarabinitol
AT yuchuyi 1deoxydarabinitol
AT watkindavidj 1deoxydarabinitol

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