Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))

Single crystals of triclinic Pr(2)(B(2)O(5))(MoO(4)) were prepared from an incongruently melting flux in the system Pr(2)O(3)–MoO(3)–B(2)O(3) in a platinum crucible in an atmosphere of air. In the crystal structure, distorted edge-sharing [PrO(8)] square anti­prisms form a three-dimensional framewor...

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Detalles Bibliográficos
Autores principales: Held, Peter, Becker, Petra
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961550/
https://www.ncbi.nlm.nih.gov/pubmed/21202431
http://dx.doi.org/10.1107/S1600536808010386
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author Held, Peter
Becker, Petra
author_facet Held, Peter
Becker, Petra
author_sort Held, Peter
collection PubMed
description Single crystals of triclinic Pr(2)(B(2)O(5))(MoO(4)) were prepared from an incongruently melting flux in the system Pr(2)O(3)–MoO(3)–B(2)O(3) in a platinum crucible in an atmosphere of air. In the crystal structure, distorted edge-sharing [PrO(8)] square anti­prisms form a three-dimensional framework. These are further linked by isolated [MoO(4)] tetra­hedra and isolated pyroborate groups [B(2)O(5)], the latter consisting of two independent trigonal [BO(3)] groups sharing one O atom. The [MoO(4)] tetra­hedra and the [B(2)O(5)] groups are arranged in alternating layers parallel to the ab plane.
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spelling pubmed-29615502010-12-30 Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4)) Held, Peter Becker, Petra Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of triclinic Pr(2)(B(2)O(5))(MoO(4)) were prepared from an incongruently melting flux in the system Pr(2)O(3)–MoO(3)–B(2)O(3) in a platinum crucible in an atmosphere of air. In the crystal structure, distorted edge-sharing [PrO(8)] square anti­prisms form a three-dimensional framework. These are further linked by isolated [MoO(4)] tetra­hedra and isolated pyroborate groups [B(2)O(5)], the latter consisting of two independent trigonal [BO(3)] groups sharing one O atom. The [MoO(4)] tetra­hedra and the [B(2)O(5)] groups are arranged in alternating layers parallel to the ab plane. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961550/ /pubmed/21202431 http://dx.doi.org/10.1107/S1600536808010386 Text en © Held and Becker 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Held, Peter
Becker, Petra
Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))
title Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))
title_full Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))
title_fullStr Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))
title_full_unstemmed Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))
title_short Dipraseodymium(III) pyroborate molybdate(VI), Pr(2)(B(2)O(5))(MoO(4))
title_sort dipraseodymium(iii) pyroborate molybdate(vi), pr(2)(b(2)o(5))(moo(4))
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961550/
https://www.ncbi.nlm.nih.gov/pubmed/21202431
http://dx.doi.org/10.1107/S1600536808010386
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