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catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]

In the crystal structure of the title complex, [Cd(N(3))(2)(C(11)H(11)N(31))(2)](n), there are two crystallographically independent Cd(II) atoms. Both exist in an octa­hedral environment composed of four N atoms of the N(3) (−) groups and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol...

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Detalles Bibliográficos
Autores principales: Guo, Ying, Cai, Hua, Li, Jiangang, Wan, Guobao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961553/
https://www.ncbi.nlm.nih.gov/pubmed/21202473
http://dx.doi.org/10.1107/S1600536808012609
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author Guo, Ying
Cai, Hua
Li, Jiangang
Wan, Guobao
author_facet Guo, Ying
Cai, Hua
Li, Jiangang
Wan, Guobao
author_sort Guo, Ying
collection PubMed
description In the crystal structure of the title complex, [Cd(N(3))(2)(C(11)H(11)N(31))(2)](n), there are two crystallographically independent Cd(II) atoms. Both exist in an octa­hedral environment composed of four N atoms of the N(3) (−) groups and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands that are positioned trans to each other. Adjacent Cd(II) centres in the crystal structure are bridged by a pair of N(3) (−) anions in a μ-1,3-fashion, forming an infinite one-dimensional array.
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spelling pubmed-29615532010-12-30 catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)] Guo, Ying Cai, Hua Li, Jiangang Wan, Guobao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cd(N(3))(2)(C(11)H(11)N(31))(2)](n), there are two crystallographically independent Cd(II) atoms. Both exist in an octa­hedral environment composed of four N atoms of the N(3) (−) groups and two N atoms from two monodentate 1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one ligands that are positioned trans to each other. Adjacent Cd(II) centres in the crystal structure are bridged by a pair of N(3) (−) anions in a μ-1,3-fashion, forming an infinite one-dimensional array. International Union of Crystallography 2008-05-07 /pmc/articles/PMC2961553/ /pubmed/21202473 http://dx.doi.org/10.1107/S1600536808012609 Text en © Guo et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Ying
Cai, Hua
Li, Jiangang
Wan, Guobao
catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]
title catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]
title_full catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]
title_fullStr catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]
title_full_unstemmed catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]
title_short catena-Poly[[bis­[1-phenyl-3-(1H-1,2,4-triazol-1-yl)propan-1-one-κN (4)]cadmium(II)]-di-μ-azido-κ(4) N (1):N (3)]
title_sort catena-poly[[bis­[1-phenyl-3-(1h-1,2,4-triazol-1-yl)propan-1-one-κn (4)]cadmium(ii)]-di-μ-azido-κ(4) n (1):n (3)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961553/
https://www.ncbi.nlm.nih.gov/pubmed/21202473
http://dx.doi.org/10.1107/S1600536808012609
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