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catena-Poly[[aquaglycolatocopper(II)]-μ-chlorido]
In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water molecule and a chloride anion comprise the basal plane. A chlo...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961558/ https://www.ncbi.nlm.nih.gov/pubmed/21202446 http://dx.doi.org/10.1107/S1600536808012166 |
Sumario: | In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water molecule and a chloride anion comprise the basal plane. A chloride ion from a neighbouring unit occupies the apical position and these Cu—Cl—Cu bridges link the aquaglycolatocopper(II) units into one-dimensional chains along the [001] direction. These chains are connected by O—H⋯O and O—H⋯Cl hydrogen bonds, forming an infinite three-dimensional polymeric network. |
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