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catena-Poly[[aqua­glycolatocopper(II)]-μ-chlorido]

In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water mol­ecule and a chloride anion comprise the basal plane. A chlo...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, John, Jain, Jebas, Samuel Robinson, Balasubramanian, T
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961558/
https://www.ncbi.nlm.nih.gov/pubmed/21202446
http://dx.doi.org/10.1107/S1600536808012166
Descripción
Sumario:In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water mol­ecule and a chloride anion comprise the basal plane. A chloride ion from a neighbouring unit occupies the apical position and these Cu—Cl—Cu bridges link the aqua­glycolatocopper(II) units into one-dimensional chains along the [001] direction. These chains are connected by O—H⋯O and O—H⋯Cl hydrogen bonds, forming an infinite three-dimensional polymeric network.