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Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate
In the molecule of the title compound, C(18)H(32)N(2)O(4), the central bicyclo[3.3.0]octane (octahydropentalene) has a rigid ring junction. Both rings of the bicyclo[3.3.0]octane unit adopt an envelope conformation, and the flexible tert-butylcarbamoyl side chains each have an extended conform...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961559/ https://www.ncbi.nlm.nih.gov/pubmed/21202657 http://dx.doi.org/10.1107/S1600536808014876 |
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author | Kendhale, Amol M. Gonnade, Rajesh G. Sanjayan, Gangadhar J. |
author_facet | Kendhale, Amol M. Gonnade, Rajesh G. Sanjayan, Gangadhar J. |
author_sort | Kendhale, Amol M. |
collection | PubMed |
description | In the molecule of the title compound, C(18)H(32)N(2)O(4), the central bicyclo[3.3.0]octane (octahydropentalene) has a rigid ring junction. Both rings of the bicyclo[3.3.0]octane unit adopt an envelope conformation, and the flexible tert-butylcarbamoyl side chains each have an extended conformation. Such a constrained bicyclo[3.3.0]octane aliphatic template is of interest with respect to the design of novel self-assembling motifs. Molecules related by c-glide symmetry are linked via intermolecular N—H⋯O hydrogen bonds, forming a two-dimensional layer structure. Neighboring layers are weakly associated along the a axis due to the close approach of the tert-butylcarbamoyl groups (2.55 Å). |
format | Text |
id | pubmed-2961559 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29615592010-12-30 Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate Kendhale, Amol M. Gonnade, Rajesh G. Sanjayan, Gangadhar J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(18)H(32)N(2)O(4), the central bicyclo[3.3.0]octane (octahydropentalene) has a rigid ring junction. Both rings of the bicyclo[3.3.0]octane unit adopt an envelope conformation, and the flexible tert-butylcarbamoyl side chains each have an extended conformation. Such a constrained bicyclo[3.3.0]octane aliphatic template is of interest with respect to the design of novel self-assembling motifs. Molecules related by c-glide symmetry are linked via intermolecular N—H⋯O hydrogen bonds, forming a two-dimensional layer structure. Neighboring layers are weakly associated along the a axis due to the close approach of the tert-butylcarbamoyl groups (2.55 Å). International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961559/ /pubmed/21202657 http://dx.doi.org/10.1107/S1600536808014876 Text en © Kendhale et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kendhale, Amol M. Gonnade, Rajesh G. Sanjayan, Gangadhar J. Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate |
title | Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate |
title_full | Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate |
title_fullStr | Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate |
title_full_unstemmed | Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate |
title_short | Di-tert-butyl N,N′-(octahydropentalene-2,5-diyl)dicarbamate |
title_sort | di-tert-butyl n,n′-(octahydropentalene-2,5-diyl)dicarbamate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961559/ https://www.ncbi.nlm.nih.gov/pubmed/21202657 http://dx.doi.org/10.1107/S1600536808014876 |
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