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Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate

In the molecule of the title compound, C(18)H(32)N(2)O(4), the central bicyclo­[3.3.0]octane (octa­hydro­penta­lene) has a rigid ring junction. Both rings of the bicyclo­[3.3.0]octane unit adopt an envelope conformation, and the flexible tert-butyl­carbamoyl side chains each have an extended conform...

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Detalles Bibliográficos
Autores principales: Kendhale, Amol M., Gonnade, Rajesh G., Sanjayan, Gangadhar J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961559/
https://www.ncbi.nlm.nih.gov/pubmed/21202657
http://dx.doi.org/10.1107/S1600536808014876
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author Kendhale, Amol M.
Gonnade, Rajesh G.
Sanjayan, Gangadhar J.
author_facet Kendhale, Amol M.
Gonnade, Rajesh G.
Sanjayan, Gangadhar J.
author_sort Kendhale, Amol M.
collection PubMed
description In the molecule of the title compound, C(18)H(32)N(2)O(4), the central bicyclo­[3.3.0]octane (octa­hydro­penta­lene) has a rigid ring junction. Both rings of the bicyclo­[3.3.0]octane unit adopt an envelope conformation, and the flexible tert-butyl­carbamoyl side chains each have an extended conformation. Such a constrained bicyclo­[3.3.0]octane aliphatic template is of inter­est with respect to the design of novel self-assembling motifs. Mol­ecules related by c-glide symmetry are linked via inter­molecular N—H⋯O hydrogen bonds, forming a two-dimensional layer structure. Neighboring layers are weakly associated along the a axis due to the close approach of the tert-butyl­carbamoyl groups (2.55 Å).
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spelling pubmed-29615592010-12-30 Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate Kendhale, Amol M. Gonnade, Rajesh G. Sanjayan, Gangadhar J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(18)H(32)N(2)O(4), the central bicyclo­[3.3.0]octane (octa­hydro­penta­lene) has a rigid ring junction. Both rings of the bicyclo­[3.3.0]octane unit adopt an envelope conformation, and the flexible tert-butyl­carbamoyl side chains each have an extended conformation. Such a constrained bicyclo­[3.3.0]octane aliphatic template is of inter­est with respect to the design of novel self-assembling motifs. Mol­ecules related by c-glide symmetry are linked via inter­molecular N—H⋯O hydrogen bonds, forming a two-dimensional layer structure. Neighboring layers are weakly associated along the a axis due to the close approach of the tert-butyl­carbamoyl groups (2.55 Å). International Union of Crystallography 2008-05-24 /pmc/articles/PMC2961559/ /pubmed/21202657 http://dx.doi.org/10.1107/S1600536808014876 Text en © Kendhale et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kendhale, Amol M.
Gonnade, Rajesh G.
Sanjayan, Gangadhar J.
Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
title Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
title_full Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
title_fullStr Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
title_full_unstemmed Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
title_short Di-tert-butyl N,N′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
title_sort di-tert-butyl n,n′-(octa­hydro­penta­lene-2,5-di­yl)dicarbamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961559/
https://www.ncbi.nlm.nih.gov/pubmed/21202657
http://dx.doi.org/10.1107/S1600536808014876
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