cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)

In the crystal structure of the title compound, [MnCl(2)(C(12)H(8)N(2))(2)]·0.5C(7)H(6)O(4)·2H(2)O, the Mn(II) complex assumes a distorted octa­hedral geometry formed by two chloride anions and two phenanthroline (phen) ligands. The 2,6-dihydroxy­benzoic acid mol­ecule is disordered about an inversi...

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Detalles Bibliográficos
Autores principales: Yang, Qian, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961560/
https://www.ncbi.nlm.nih.gov/pubmed/21202450
http://dx.doi.org/10.1107/S1600536808012427
Descripción
Sumario:In the crystal structure of the title compound, [MnCl(2)(C(12)H(8)N(2))(2)]·0.5C(7)H(6)O(4)·2H(2)O, the Mn(II) complex assumes a distorted octa­hedral geometry formed by two chloride anions and two phenanthroline (phen) ligands. The 2,6-dihydroxy­benzoic acid mol­ecule is disordered about an inversion center. The face-to-face separations of 3.540 (11) and 3.429 (8) Å between parallel phen ligands indicate the existence of π–π stacking between adjacent Mn(II) complexes. Uncoordinated water mol­ecules are linked with complex and dihydroxy­benzoic acid mol­ecules via O—H⋯Cl and O—H⋯O hydrogen bonds.

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