cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)

In the crystal structure of the title compound, [MnCl(2)(C(12)H(8)N(2))(2)]·0.5C(7)H(6)O(4)·2H(2)O, the Mn(II) complex assumes a distorted octa­hedral geometry formed by two chloride anions and two phenanthroline (phen) ligands. The 2,6-dihydroxy­benzoic acid mol­ecule is disordered about an inversi...

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Detalles Bibliográficos
Autores principales: Yang, Qian, Nie, Jing-Jing, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961560/
https://www.ncbi.nlm.nih.gov/pubmed/21202450
http://dx.doi.org/10.1107/S1600536808012427
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author Yang, Qian
Nie, Jing-Jing
Xu, Duan-Jun
author_facet Yang, Qian
Nie, Jing-Jing
Xu, Duan-Jun
author_sort Yang, Qian
collection PubMed
description In the crystal structure of the title compound, [MnCl(2)(C(12)H(8)N(2))(2)]·0.5C(7)H(6)O(4)·2H(2)O, the Mn(II) complex assumes a distorted octa­hedral geometry formed by two chloride anions and two phenanthroline (phen) ligands. The 2,6-dihydroxy­benzoic acid mol­ecule is disordered about an inversion center. The face-to-face separations of 3.540 (11) and 3.429 (8) Å between parallel phen ligands indicate the existence of π–π stacking between adjacent Mn(II) complexes. Uncoordinated water mol­ecules are linked with complex and dihydroxy­benzoic acid mol­ecules via O—H⋯Cl and O—H⋯O hydrogen bonds.
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spelling pubmed-29615602010-12-30 cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4) Yang, Qian Nie, Jing-Jing Xu, Duan-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [MnCl(2)(C(12)H(8)N(2))(2)]·0.5C(7)H(6)O(4)·2H(2)O, the Mn(II) complex assumes a distorted octa­hedral geometry formed by two chloride anions and two phenanthroline (phen) ligands. The 2,6-dihydroxy­benzoic acid mol­ecule is disordered about an inversion center. The face-to-face separations of 3.540 (11) and 3.429 (8) Å between parallel phen ligands indicate the existence of π–π stacking between adjacent Mn(II) complexes. Uncoordinated water mol­ecules are linked with complex and dihydroxy­benzoic acid mol­ecules via O—H⋯Cl and O—H⋯O hydrogen bonds. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961560/ /pubmed/21202450 http://dx.doi.org/10.1107/S1600536808012427 Text en © Yang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Qian
Nie, Jing-Jing
Xu, Duan-Jun
cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)
title cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)
title_full cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)
title_fullStr cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)
title_full_unstemmed cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)
title_short cis-Dichloridobis(1,10-phenanthroline-κ(2) N,N′)manganese(II)–2,6-dihydroxy­benzoic acid–water (2/1/4)
title_sort cis-dichloridobis(1,10-phenanthroline-κ(2) n,n′)manganese(ii)–2,6-dihydroxy­benzoic acid–water (2/1/4)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961560/
https://www.ncbi.nlm.nih.gov/pubmed/21202450
http://dx.doi.org/10.1107/S1600536808012427
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AT xuduanjun cisdichloridobis110phenanthrolinek2nnmanganeseii26dihydroxybenzoicacidwater214

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