(4S,8S,9R,12E)-8,9,16,18-Tetrahydroxy-4-methyl-3-oxabicyclo[12.4.0]octadeca-12,14,16,18-tetraen-2-one monohydrate

The asymmetric unit of the title compound, C(18)H(24)O(6)·H(2)O, contains a 14-membered macrolide mol­ecule and a water mol­ecule. In the crystal structure, intra­molecular C—H⋯O and O—H⋯O hydrogen bonds help to stabilize the mol­ecular conformation, while inter­molecular O—H⋯O hydrogen bonds link t...

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Detalles Bibliográficos
Autores principales: Zhao, Ling-Ling, Gai, Yue, Kobayashi, Hisayoshi, Hu, Chang-Qi, Zhang, Hui-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961568/
https://www.ncbi.nlm.nih.gov/pubmed/21202724
http://dx.doi.org/10.1107/S1600536808010258
Descripción
Sumario:The asymmetric unit of the title compound, C(18)H(24)O(6)·H(2)O, contains a 14-membered macrolide mol­ecule and a water mol­ecule. In the crystal structure, intra­molecular C—H⋯O and O—H⋯O hydrogen bonds help to stabilize the mol­ecular conformation, while inter­molecular O—H⋯O hydrogen bonds link the mol­ecules, forming an infinite network. The absolute configuration was assigned by comparison with related zearalenone compounds, but needs verification.

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