Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate

In the title compound, [Zr(C(5)H(4)F(3)O(2))(4)]·C(7)H(8), the Zr atom is in a square-anti­prismatic coordination geometry that comprises four O,O′-bidentate trifluoro­acetyl­acetonate ligands. The O—Zr—O bite angles of the acetonate ligands range from 75.27 (5) to 75.41 (5)°. The Zr atom is located...

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Detalles Bibliográficos
Autores principales: Steyn, Maryke, Roodt, Andreas, Steyl, Gideon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961572/
https://www.ncbi.nlm.nih.gov/pubmed/21202509
http://dx.doi.org/10.1107/S1600536808014499
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author Steyn, Maryke
Roodt, Andreas
Steyl, Gideon
author_facet Steyn, Maryke
Roodt, Andreas
Steyl, Gideon
author_sort Steyn, Maryke
collection PubMed
description In the title compound, [Zr(C(5)H(4)F(3)O(2))(4)]·C(7)H(8), the Zr atom is in a square-anti­prismatic coordination geometry that comprises four O,O′-bidentate trifluoro­acetyl­acetonate ligands. The O—Zr—O bite angles of the acetonate ligands range from 75.27 (5) to 75.41 (5)°. The Zr atom is located on a twofold rotation axis.
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spelling pubmed-29615722010-12-30 Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate Steyn, Maryke Roodt, Andreas Steyl, Gideon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zr(C(5)H(4)F(3)O(2))(4)]·C(7)H(8), the Zr atom is in a square-anti­prismatic coordination geometry that comprises four O,O′-bidentate trifluoro­acetyl­acetonate ligands. The O—Zr—O bite angles of the acetonate ligands range from 75.27 (5) to 75.41 (5)°. The Zr atom is located on a twofold rotation axis. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961572/ /pubmed/21202509 http://dx.doi.org/10.1107/S1600536808014499 Text en © Steyn et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Steyn, Maryke
Roodt, Andreas
Steyl, Gideon
Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate
title Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate
title_full Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate
title_fullStr Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate
title_full_unstemmed Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate
title_short Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) O,O′)zirconium(IV) toluene solvate
title_sort tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ(2) o,o′)zirconium(iv) toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961572/
https://www.ncbi.nlm.nih.gov/pubmed/21202509
http://dx.doi.org/10.1107/S1600536808014499
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AT roodtandreas tetrakis111trifluoroacetylacetonatok2oozirconiumivtoluenesolvate
AT steylgideon tetrakis111trifluoroacetylacetonatok2oozirconiumivtoluenesolvate

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