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(E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone
In the title compound, C(15)H(15)N(3)OS, the thiosemicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961576/ https://www.ncbi.nlm.nih.gov/pubmed/21202714 http://dx.doi.org/10.1107/S1600536808012671 |
Sumario: | In the title compound, C(15)H(15)N(3)OS, the thiosemicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)°. In the crystal structure, molecules are interconnected by N—H⋯N and N—H⋯S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by π–π interactions [centroid–centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C—H⋯π interactions. |
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