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(E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone
In the title compound, C(15)H(15)N(3)OS, the thiosemicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961576/ https://www.ncbi.nlm.nih.gov/pubmed/21202714 http://dx.doi.org/10.1107/S1600536808012671 |
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author | Tarafder, M. T. H. Islam, M. A. A. A. A. Crouse, K. A. Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Tarafder, M. T. H. Islam, M. A. A. A. A. Crouse, K. A. Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Tarafder, M. T. H. |
collection | PubMed |
description | In the title compound, C(15)H(15)N(3)OS, the thiosemicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)°. In the crystal structure, molecules are interconnected by N—H⋯N and N—H⋯S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by π–π interactions [centroid–centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C—H⋯π interactions. |
format | Text |
id | pubmed-2961576 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29615762010-12-30 (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone Tarafder, M. T. H. Islam, M. A. A. A. A. Crouse, K. A. Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)N(3)OS, the thiosemicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thiosemicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benzyloxy and phenyl rings is 72.48 (5)°. In the crystal structure, molecules are interconnected by N—H⋯N and N—H⋯S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by π–π interactions [centroid–centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C—H⋯π interactions. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961576/ /pubmed/21202714 http://dx.doi.org/10.1107/S1600536808012671 Text en © Tarafder et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tarafder, M. T. H. Islam, M. A. A. A. A. Crouse, K. A. Chantrapromma, Suchada Fun, Hoong-Kun (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone |
title | (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone |
title_full | (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone |
title_fullStr | (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone |
title_full_unstemmed | (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone |
title_short | (E)-4-(Benzyloxy)benzaldehyde thiosemicarbazone |
title_sort | (e)-4-(benzyloxy)benzaldehyde thiosemicarbazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961576/ https://www.ncbi.nlm.nih.gov/pubmed/21202714 http://dx.doi.org/10.1107/S1600536808012671 |
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