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(E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone

In the title compound, C(15)H(15)N(3)OS, the thio­semicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thio­semicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benz­yloxy and phenyl rings is 72.48 (5)...

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Detalles Bibliográficos
Autores principales: Tarafder, M. T. H., Islam, M. A. A. A. A., Crouse, K. A., Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961576/
https://www.ncbi.nlm.nih.gov/pubmed/21202714
http://dx.doi.org/10.1107/S1600536808012671
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author Tarafder, M. T. H.
Islam, M. A. A. A. A.
Crouse, K. A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Tarafder, M. T. H.
Islam, M. A. A. A. A.
Crouse, K. A.
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Tarafder, M. T. H.
collection PubMed
description In the title compound, C(15)H(15)N(3)OS, the thio­semicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thio­semicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benz­yloxy and phenyl rings is 72.48 (5)°. In the crystal structure, mol­ecules are inter­connected by N—H⋯N and N—H⋯S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by π–π inter­actions [centroid–centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C—H⋯π inter­actions.
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spelling pubmed-29615762010-12-30 (E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone Tarafder, M. T. H. Islam, M. A. A. A. A. Crouse, K. A. Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)N(3)OS, the thio­semicarbazone group adopts an E configuration with respect to the C=N bond. The benzaldehyde thio­semicarbazone fragment is almost planar [maximum deviation = 0.012 (1) Å], while the dihedral angle between the benz­yloxy and phenyl rings is 72.48 (5)°. In the crystal structure, mol­ecules are inter­connected by N—H⋯N and N—H⋯S hydrogen bonds, forming a two-dimensional network parallel to the bc plane and are further stacked along the a axis by π–π inter­actions [centroid–centroid separation 3.9043 (7) Å]. The crystal structure is also stabilized by C—H⋯π inter­actions. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961576/ /pubmed/21202714 http://dx.doi.org/10.1107/S1600536808012671 Text en © Tarafder et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tarafder, M. T. H.
Islam, M. A. A. A. A.
Crouse, K. A.
Chantrapromma, Suchada
Fun, Hoong-Kun
(E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone
title (E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone
title_full (E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone
title_fullStr (E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone
title_full_unstemmed (E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone
title_short (E)-4-(Benz­yloxy)benzaldehyde thio­semicarbazone
title_sort (e)-4-(benz­yloxy)benzaldehyde thio­semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961576/
https://www.ncbi.nlm.nih.gov/pubmed/21202714
http://dx.doi.org/10.1107/S1600536808012671
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