Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate

In the title complex, [Ni(NCS)(2)(C(14)H(13)N(3))(2)]·2CH(3)OH, the Ni(II) atom lies on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral NiN(6) coordination environment. The crystal structure is stabilized by a combination of weak π–π stacking inter­actions between...

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Detalles Bibliográficos
Autores principales: Zhang, Shi Guo, Hu, Tai Qiu, Li, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961583/
https://www.ncbi.nlm.nih.gov/pubmed/21202461
http://dx.doi.org/10.1107/S1600536808011811
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author Zhang, Shi Guo
Hu, Tai Qiu
Li, Hong
author_facet Zhang, Shi Guo
Hu, Tai Qiu
Li, Hong
author_sort Zhang, Shi Guo
collection PubMed
description In the title complex, [Ni(NCS)(2)(C(14)H(13)N(3))(2)]·2CH(3)OH, the Ni(II) atom lies on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral NiN(6) coordination environment. The crystal structure is stabilized by a combination of weak π–π stacking inter­actions between symmetry-related 1,10-phenanthroline ligands [centroi–centroid distance between benzene rings = 3.5936 (18) Å] and weak O—H⋯S, C—H⋯O and C—H⋯S hydrogen bonds between methanol and complex mol­ecules.
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spelling pubmed-29615832010-12-30 Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate Zhang, Shi Guo Hu, Tai Qiu Li, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(NCS)(2)(C(14)H(13)N(3))(2)]·2CH(3)OH, the Ni(II) atom lies on a crystallographic twofold rotation axis and is in a slightly distorted octa­hedral NiN(6) coordination environment. The crystal structure is stabilized by a combination of weak π–π stacking inter­actions between symmetry-related 1,10-phenanthroline ligands [centroi–centroid distance between benzene rings = 3.5936 (18) Å] and weak O—H⋯S, C—H⋯O and C—H⋯S hydrogen bonds between methanol and complex mol­ecules. International Union of Crystallography 2008-05-03 /pmc/articles/PMC2961583/ /pubmed/21202461 http://dx.doi.org/10.1107/S1600536808011811 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Shi Guo
Hu, Tai Qiu
Li, Hong
Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate
title Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate
title_full Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate
title_fullStr Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate
title_full_unstemmed Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate
title_short Bis(2-dimethylamino-1,10-phenanthroline-κ(2) N,N′)bis­(thio­cyanato-κN)nickel(II) methanol disolvate
title_sort bis(2-dimethylamino-1,10-phenanthroline-κ(2) n,n′)bis­(thio­cyanato-κn)nickel(ii) methanol disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961583/
https://www.ncbi.nlm.nih.gov/pubmed/21202461
http://dx.doi.org/10.1107/S1600536808011811
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AT hutaiqiu bis2dimethylamino110phenanthrolinek2nnbisthiocyanatoknnickeliimethanoldisolvate
AT lihong bis2dimethylamino110phenanthrolinek2nnbisthiocyanatoknnickeliimethanoldisolvate

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