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(1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol

A new tetra­dentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenyl­butane-1,3-dione with (1S,2S)-(−)-1,2-diamino­cyclo­hexane. The chiral centers in the mol­ecule have the same S configuration, since the absolute configuration was determined by that o...

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Detalles Bibliográficos
Autores principales: Li, Xiu-Zhi, Qu, Zhi-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961585/
https://www.ncbi.nlm.nih.gov/pubmed/21202632
http://dx.doi.org/10.1107/S1600536808014670
Descripción
Sumario:A new tetra­dentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenyl­butane-1,3-dione with (1S,2S)-(−)-1,2-diamino­cyclo­hexane. The chiral centers in the mol­ecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(−)-1,2-diamino­hexane. The cyclo­hexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclo­hexyl). The crystal structure is stabilized by two intra­molecular O—H⋯N hydrogen bonds and a weak C—H⋯π inter­action.