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(1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol
A new tetradentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenylbutane-1,3-dione with (1S,2S)-(−)-1,2-diaminocyclohexane. The chiral centers in the molecule have the same S configuration, since the absolute configuration was determined by that o...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961585/ https://www.ncbi.nlm.nih.gov/pubmed/21202632 http://dx.doi.org/10.1107/S1600536808014670 |
Sumario: | A new tetradentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenylbutane-1,3-dione with (1S,2S)-(−)-1,2-diaminocyclohexane. The chiral centers in the molecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(−)-1,2-diaminohexane. The cyclohexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclohexyl). The crystal structure is stabilized by two intramolecular O—H⋯N hydrogen bonds and a weak C—H⋯π interaction. |
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