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(1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol
A new tetradentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenylbutane-1,3-dione with (1S,2S)-(−)-1,2-diaminocyclohexane. The chiral centers in the molecule have the same S configuration, since the absolute configuration was determined by that o...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961585/ https://www.ncbi.nlm.nih.gov/pubmed/21202632 http://dx.doi.org/10.1107/S1600536808014670 |
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author | Li, Xiu-Zhi Qu, Zhi-Rong |
author_facet | Li, Xiu-Zhi Qu, Zhi-Rong |
author_sort | Li, Xiu-Zhi |
collection | PubMed |
description | A new tetradentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenylbutane-1,3-dione with (1S,2S)-(−)-1,2-diaminocyclohexane. The chiral centers in the molecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(−)-1,2-diaminohexane. The cyclohexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclohexyl). The crystal structure is stabilized by two intramolecular O—H⋯N hydrogen bonds and a weak C—H⋯π interaction. |
format | Text |
id | pubmed-2961585 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29615852010-12-30 (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol Li, Xiu-Zhi Qu, Zhi-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers A new tetradentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenylbutane-1,3-dione with (1S,2S)-(−)-1,2-diaminocyclohexane. The chiral centers in the molecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(−)-1,2-diaminohexane. The cyclohexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclohexyl). The crystal structure is stabilized by two intramolecular O—H⋯N hydrogen bonds and a weak C—H⋯π interaction. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961585/ /pubmed/21202632 http://dx.doi.org/10.1107/S1600536808014670 Text en © Li and Qu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Xiu-Zhi Qu, Zhi-Rong (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
title | (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
title_full | (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
title_fullStr | (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
title_full_unstemmed | (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
title_short | (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
title_sort | (1z,1′z,3e,3′e)-1,1′-diphenyl-3,3′-[(1s,2s)-cyclohexane-1,2-diyldinitrilo]dibut-1-en-1-ol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961585/ https://www.ncbi.nlm.nih.gov/pubmed/21202632 http://dx.doi.org/10.1107/S1600536808014670 |
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