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(1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol

A new tetra­dentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenyl­butane-1,3-dione with (1S,2S)-(−)-1,2-diamino­cyclo­hexane. The chiral centers in the mol­ecule have the same S configuration, since the absolute configuration was determined by that o...

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Detalles Bibliográficos
Autores principales: Li, Xiu-Zhi, Qu, Zhi-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961585/
https://www.ncbi.nlm.nih.gov/pubmed/21202632
http://dx.doi.org/10.1107/S1600536808014670
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author Li, Xiu-Zhi
Qu, Zhi-Rong
author_facet Li, Xiu-Zhi
Qu, Zhi-Rong
author_sort Li, Xiu-Zhi
collection PubMed
description A new tetra­dentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenyl­butane-1,3-dione with (1S,2S)-(−)-1,2-diamino­cyclo­hexane. The chiral centers in the mol­ecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(−)-1,2-diamino­hexane. The cyclo­hexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclo­hexyl). The crystal structure is stabilized by two intra­molecular O—H⋯N hydrogen bonds and a weak C—H⋯π inter­action.
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spelling pubmed-29615852010-12-30 (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol Li, Xiu-Zhi Qu, Zhi-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers A new tetra­dentate chiral Schiff base ligand, C(26)H(30)N(2)O(2), has been synthesized by the reaction of 1-phenyl­butane-1,3-dione with (1S,2S)-(−)-1,2-diamino­cyclo­hexane. The chiral centers in the mol­ecule have the same S configuration, since the absolute configuration was determined by that of the starting reagent (1S,2S)-(−)-1,2-diamino­hexane. The cyclo­hexane ring is in a chair conformation, and the substituents are equatorial in the most stable conformation (trans-cyclo­hexyl). The crystal structure is stabilized by two intra­molecular O—H⋯N hydrogen bonds and a weak C—H⋯π inter­action. International Union of Crystallography 2008-05-21 /pmc/articles/PMC2961585/ /pubmed/21202632 http://dx.doi.org/10.1107/S1600536808014670 Text en © Li and Qu 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xiu-Zhi
Qu, Zhi-Rong
(1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
title (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
title_full (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
title_fullStr (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
title_full_unstemmed (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
title_short (1Z,1′Z,3E,3′E)-1,1′-Diphenyl-3,3′-[(1S,2S)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
title_sort (1z,1′z,3e,3′e)-1,1′-diphenyl-3,3′-[(1s,2s)-cyclo­hexane-1,2-diyldinitrilo]dibut-1-en-1-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961585/
https://www.ncbi.nlm.nih.gov/pubmed/21202632
http://dx.doi.org/10.1107/S1600536808014670
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